TY - JOUR
T1 - Zinc Oxide Nanocomposites of Selected Polymers
T2 - Synthesis, Characterization, and Corrosion Inhibition Studies on Mild Steel in HCl Solution
AU - Quadri, Taiwo W.
AU - Olasunkanmi, Lukman O.
AU - Fayemi, Omolola E.
AU - Solomon, Moses M.
AU - Ebenso, Eno E.
N1 - Publisher Copyright:
© 2017 American Chemical Society.
PY - 2017/11/30
Y1 - 2017/11/30
N2 - Nanocomposites of ZnO and some selected polymers, namely, poly(ethylene glycol), poly(vinylpyrrolidone), and polyacrylonitrile, were synthesized and characterized using Fourier transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy, thermogravimetric analysis (TGA), and transmission electron microscopy (TEM) techniques. The FTIR and UV-vis spectra confirmed the successful formation of the polymer nanocomposites. TGA results revealed that the synthesized polymer nanocomposites are more thermally stable than the polymers alone. ZnO nanoparticles were about 50-75 nm in size, assumed a rodlike shape, and got embedded in the polymer matrices, as revealed by TEM images. Corrosion inhibition potentials of the synthesized ZnO/polymer nanocomposites were investigated for mild steel in 5% HCl solution using potentiodynamic polarization (PDP), linear polarization resistance, and electrochemical impedance spectroscopy measurements. The results showed that each ZnO/polymer nanocomposite inhibits mild steel corrosion in 5% HCl solution better than the respective polymer alone. The nanocomposites, according to PDP studies, behaved as a mixed-type inhibitor. The predominant mode of adsorption of the nanocomposites to a mild steel surface was found to be mixed type, and the adsorption process obeys the Langmuir adsorption isotherm model. Scanning electron microscopy images also revealed the protective attributes of the ZnO/polymer nanocomposites for mild steel in 5% HCl solution.
AB - Nanocomposites of ZnO and some selected polymers, namely, poly(ethylene glycol), poly(vinylpyrrolidone), and polyacrylonitrile, were synthesized and characterized using Fourier transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy, thermogravimetric analysis (TGA), and transmission electron microscopy (TEM) techniques. The FTIR and UV-vis spectra confirmed the successful formation of the polymer nanocomposites. TGA results revealed that the synthesized polymer nanocomposites are more thermally stable than the polymers alone. ZnO nanoparticles were about 50-75 nm in size, assumed a rodlike shape, and got embedded in the polymer matrices, as revealed by TEM images. Corrosion inhibition potentials of the synthesized ZnO/polymer nanocomposites were investigated for mild steel in 5% HCl solution using potentiodynamic polarization (PDP), linear polarization resistance, and electrochemical impedance spectroscopy measurements. The results showed that each ZnO/polymer nanocomposite inhibits mild steel corrosion in 5% HCl solution better than the respective polymer alone. The nanocomposites, according to PDP studies, behaved as a mixed-type inhibitor. The predominant mode of adsorption of the nanocomposites to a mild steel surface was found to be mixed type, and the adsorption process obeys the Langmuir adsorption isotherm model. Scanning electron microscopy images also revealed the protective attributes of the ZnO/polymer nanocomposites for mild steel in 5% HCl solution.
UR - http://www.scopus.com/inward/record.url?scp=85044766662&partnerID=8YFLogxK
U2 - 10.1021/acsomega.7b01385
DO - 10.1021/acsomega.7b01385
M3 - Article
AN - SCOPUS:85044766662
SN - 2470-1343
VL - 2
SP - 8421
EP - 8437
JO - ACS Omega
JF - ACS Omega
IS - 11
ER -