Promotional effects of calcination temperature and H₂O on the catalytic activity of Al-substituted MnAlO catalysts for low-temperature acetone oxidation

In order to enhance the role of Al in the materials, Al-substituted MnAlO catalysts were synthesized via the hydrothermal-redox method at different calcination temperatures for acetone oxidation. There were Al-substituted α-MnO₂ and amorphous aluminum oxide existed with homogeneous dispersion of elements in the catalysts. The surface property, reaction rate, CO₂ yield and water resistance of MnAlO catalysts were greatly affected by calcination temperatures. MnAlO-450 catalyst exhibited the best catalytic performance (acetone conversion of 90% at 165 °C) with CO₂ yield higher than 99.7%, which was mainly related to the weaker Mn–O bond strength, lower temperature reducibility and abundant Lewis acid sites. The acetone conversion of MnAlO-450 increased by as much as 16% in the presence of 1 vol% H₂O compared to that in the absence of H₂O at T₅₀ (the temperature for 50% conversion of acetone). The acceleration consumption of ethanol as the main by-product by H₂O improved the catalytic performance. This work would shed light on the Al substitution based catalysts for OVOC oxidation with highly efficient and water resistance.