Effect of intensifier additives on the performance of butanolic extract of date palm leaves against the corrosion of api 5l x60 carbon steel in 15 wt.% hcl solution

The quest to replace toxic chemicals in the nearest future is revolutionizing the corrosion inhibitor research world by turning its attention to plant biomaterials. Herein, we report the corrosion inhibiting potential of butanolic extract of date palm leaves (BUT) on the corrosion of API 5L X60 carbon steel in 15 wt.% HCl solution. The mass loss, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), linear polarization (LPR), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDAX), and atomic force microscopy (AFM) techniques were employed in the investigation. We also report the effect of intensifier additives, namely formic acid (FA), potassium iodide (KI), and zinc nitrate (Zn(NO₃ )₂ ) as well as temperature on the corrosion inhibiting performance of BUT. BUT exhibits inhibiting ability but the extent of inhibition is dependent on concentration, temperature, and intensifiers’ concentration. At 25^◦ C, 200 mg/L BUT and 700 mg/L BUT protected the carbon steel surface by 50% and 88%, respectively. The addition of 3 mM FA and 5 mM KI to 200 mg/L upgraded the extract performance to 97% and 95%, respectively. Zn(NO₃ )₂ performs poorly as an intensifier for BUT under acidizing conditions. The adsorption of BUT + FA and BUT + KI is synergistic in nature whereas that of BUT + Zn(NO₃ )₂ drifts towards antagonistic behavior according to the calculated synergism parameter. Increase in the system temperature resulted in a slight decline in the inhibition efficiency of BUT + FA and BUT + KI but with efficiency of above 85% achieved at 60^◦ C. The SEM and AFM results corroborate results from the electrochemical techniques.