Comparative studies of the corrosion inhibition efficacy of a dicationic monomer and its polymer against API X60 steel corrosion in simulated acidizing fluid under static and hydrodynamic conditions

Nurudeen A. Odewunmi; Moses M. Solomon; Saviour A. Umoren; Shaikh A. Ali

doi:10.1021/acsomega.0c02345

Comparative studies of the corrosion inhibition efficacy of a dicationic monomer and its polymer against API X60 steel corrosion in simulated acidizing fluid under static and hydrodynamic conditions

Nurudeen A. Odewunmi, Moses M. Solomon, Saviour A. Umoren, Shaikh A. Ali

Research output: Journal Publication › Article › peer-review

50 Citations (Scopus)

Abstract

N¹,N¹-diallyl-N⁶,N⁶,N⁶-tripropylhexane-1,6-diaminium chloride (NDTHDC) and its polymer poly(N¹,N¹-diallyl-N⁶,N⁶,N⁶-tripropylhexane-1,6-diaminium chloride) (poly-NDTHDC) were synthesized and tested against API X60 carbon steel corrosion in 15 wt % HCl solution. Weight loss, electrochemical, and surface analysis techniques were used. Results show that poly-NDTHDC is better than NDTHDC. Moreover, 1000 mg/L NDTHDC protected the studied surface by 79.1% at 25 °C, while 100 mg/L poly-NDTHDC afforded 86.1% protection. Inhibition efficiency increases with temperature (up to 60 °C) but depreciates thereafter. NDTHDC and poly-NDTHDC perform better under the hydrodynamic condition than the static condition. TGA and FTIR results reveal that poly-NDTHDC is chemically and thermally stable.

Original language	English
Pages (from-to)	27057-27071
Number of pages	15
Journal	ACS Omega
Volume	5
Issue number	42
DOIs	https://doi.org/10.1021/acsomega.0c02345
Publication status	Published - 27 Oct 2020
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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@article{0a46aed6be7748668e565d7ebafd1332,

title = "Comparative studies of the corrosion inhibition efficacy of a dicationic monomer and its polymer against API X60 steel corrosion in simulated acidizing fluid under static and hydrodynamic conditions",

abstract = "N1,N1-diallyl-N6,N6,N6-tripropylhexane-1,6-diaminium chloride (NDTHDC) and its polymer poly(N1,N1-diallyl-N6,N6,N6-tripropylhexane-1,6-diaminium chloride) (poly-NDTHDC) were synthesized and tested against API X60 carbon steel corrosion in 15 wt % HCl solution. Weight loss, electrochemical, and surface analysis techniques were used. Results show that poly-NDTHDC is better than NDTHDC. Moreover, 1000 mg/L NDTHDC protected the studied surface by 79.1% at 25 °C, while 100 mg/L poly-NDTHDC afforded 86.1% protection. Inhibition efficiency increases with temperature (up to 60 °C) but depreciates thereafter. NDTHDC and poly-NDTHDC perform better under the hydrodynamic condition than the static condition. TGA and FTIR results reveal that poly-NDTHDC is chemically and thermally stable.",

author = "Odewunmi, {Nurudeen A.} and Solomon, {Moses M.} and Umoren, {Saviour A.} and Ali, {Shaikh A.}",

note = "Publisher Copyright: {\textcopyright} 2020 American Chemical Society",

year = "2020",

month = oct,

day = "27",

doi = "10.1021/acsomega.0c02345",

language = "English",

volume = "5",

pages = "27057--27071",

journal = "ACS Omega",

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Comparative studies of the corrosion inhibition efficacy of a dicationic monomer and its polymer against API X60 steel corrosion in simulated acidizing fluid under static and hydrodynamic conditions. / Odewunmi, Nurudeen A.; Solomon, Moses M.; Umoren, Saviour A. et al.
In: ACS Omega, Vol. 5, No. 42, 27.10.2020, p. 27057-27071.

Research output: Journal Publication › Article › peer-review

TY - JOUR

T1 - Comparative studies of the corrosion inhibition efficacy of a dicationic monomer and its polymer against API X60 steel corrosion in simulated acidizing fluid under static and hydrodynamic conditions

AU - Odewunmi, Nurudeen A.

AU - Solomon, Moses M.

AU - Umoren, Saviour A.

AU - Ali, Shaikh A.

PY - 2020/10/27

Y1 - 2020/10/27

N2 - N1,N1-diallyl-N6,N6,N6-tripropylhexane-1,6-diaminium chloride (NDTHDC) and its polymer poly(N1,N1-diallyl-N6,N6,N6-tripropylhexane-1,6-diaminium chloride) (poly-NDTHDC) were synthesized and tested against API X60 carbon steel corrosion in 15 wt % HCl solution. Weight loss, electrochemical, and surface analysis techniques were used. Results show that poly-NDTHDC is better than NDTHDC. Moreover, 1000 mg/L NDTHDC protected the studied surface by 79.1% at 25 °C, while 100 mg/L poly-NDTHDC afforded 86.1% protection. Inhibition efficiency increases with temperature (up to 60 °C) but depreciates thereafter. NDTHDC and poly-NDTHDC perform better under the hydrodynamic condition than the static condition. TGA and FTIR results reveal that poly-NDTHDC is chemically and thermally stable.

AB - N1,N1-diallyl-N6,N6,N6-tripropylhexane-1,6-diaminium chloride (NDTHDC) and its polymer poly(N1,N1-diallyl-N6,N6,N6-tripropylhexane-1,6-diaminium chloride) (poly-NDTHDC) were synthesized and tested against API X60 carbon steel corrosion in 15 wt % HCl solution. Weight loss, electrochemical, and surface analysis techniques were used. Results show that poly-NDTHDC is better than NDTHDC. Moreover, 1000 mg/L NDTHDC protected the studied surface by 79.1% at 25 °C, while 100 mg/L poly-NDTHDC afforded 86.1% protection. Inhibition efficiency increases with temperature (up to 60 °C) but depreciates thereafter. NDTHDC and poly-NDTHDC perform better under the hydrodynamic condition than the static condition. TGA and FTIR results reveal that poly-NDTHDC is chemically and thermally stable.

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Comparative studies of the corrosion inhibition efficacy of a dicationic monomer and its polymer against API X60 steel corrosion in simulated acidizing fluid under static and hydrodynamic conditions

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