Two photochemical pathways in competition: Matrix isolation, time- resolved and NMR studies of cis-[Ru(PMe3)4(H)2]

Virginia Montiel-Palma; Robin N. Perutz; Michael W. George; Omar S. Jina; Sylviane Sabo-Etienne

doi:10.1039/b002297g

Two photochemical pathways in competition: Matrix isolation, time- resolved and NMR studies of cis-[Ru(PMe₃)₄(H)₂]

Virginia Montiel-Palma, Robin N. Perutz, Michael W. George, Omar S. Jina, Sylviane Sabo-Etienne

Research output: Journal Publication › Article › peer-review

21 Citations (Scopus)

Abstract

cis-[Ru(PMe₃)₄(H)₂] (1) reacts by two distinct photochemical pathways resulting in the formation of [Ru(PMe₃)₄] and [Ru(PMe₃)₃(H)₂]; derivatives of these intermediates are generated in the presence of CO and Ph₂SiH₂.

Original language	English
Pages (from-to)	1175-1176
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/b002297g
Publication status	Published - 7 Jul 2000
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b002297g

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title = "Two photochemical pathways in competition: Matrix isolation, time- resolved and NMR studies of cis-[Ru(PMe3)4(H)2]",

abstract = "cis-[Ru(PMe3)4(H)2] (1) reacts by two distinct photochemical pathways resulting in the formation of [Ru(PMe3)4] and [Ru(PMe3)3(H)2]; derivatives of these intermediates are generated in the presence of CO and Ph2SiH2.",

author = "Virginia Montiel-Palma and Perutz, {Robin N.} and George, {Michael W.} and Jina, {Omar S.} and Sylviane Sabo-Etienne",

year = "2000",

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doi = "10.1039/b002297g",

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publisher = "Royal Society of Chemistry",

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T2 - Matrix isolation, time- resolved and NMR studies of cis-[Ru(PMe3)4(H)2]

AU - Montiel-Palma, Virginia

AU - Perutz, Robin N.

AU - George, Michael W.

AU - Jina, Omar S.

AU - Sabo-Etienne, Sylviane

PY - 2000/7/7

Y1 - 2000/7/7

N2 - cis-[Ru(PMe3)4(H)2] (1) reacts by two distinct photochemical pathways resulting in the formation of [Ru(PMe3)4] and [Ru(PMe3)3(H)2]; derivatives of these intermediates are generated in the presence of CO and Ph2SiH2.

AB - cis-[Ru(PMe3)4(H)2] (1) reacts by two distinct photochemical pathways resulting in the formation of [Ru(PMe3)4] and [Ru(PMe3)3(H)2]; derivatives of these intermediates are generated in the presence of CO and Ph2SiH2.

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JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Two photochemical pathways in competition: Matrix isolation, time- resolved and NMR studies of cis-[Ru(PMe₃)₄(H)₂]

Abstract

ASJC Scopus subject areas

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