Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

Mark R. Warren; Simon K. Brayshaw; Andrew L. Johnson; Stefanie Schiffers; Paul R. Raithby; Timothy L. Easun; Michael W. George; John E. Warren; Simon J. Teat

doi:10.1002/anie.200901706

Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η¹-ONO)C1] isomer

Mark R. Warren, Simon K. Brayshaw, Andrew L. Johnson, Stefanie Schiffers, Paul R. Raithby, Timothy L. Easun, Michael W. George, John E. Warren, Simon J. Teat

Research output: Journal Publication › Article › peer-review

77 Citations (Scopus)

Abstract

Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η¹-NO₂)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η¹-ONO)Cl] isomer.

Original language	English
Pages (from-to)	5711-5714
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	31
DOIs	https://doi.org/10.1002/anie.200901706
Publication status	Published - 20 Jul 2009
Externally published	Yes

Keywords

Linkage isomerism
Metastable compounds
Nitrites
Photocrystallography
Raman spectroscopy

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200901706

Cite this

Warren, M. R., Brayshaw, S. K., Johnson, A. L., Schiffers, S., Raithby, P. R., Easun, T. L., George, M. W., Warren, J. E., & Teat, S. J. (2009). Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η¹-ONO)C1] isomer. Angewandte Chemie - International Edition, 48(31), 5711-5714. https://doi.org/10.1002/anie.200901706

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title = "Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer",

abstract = "Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer.",

keywords = "Linkage isomerism, Metastable compounds, Nitrites, Photocrystallography, Raman spectroscopy",

author = "Warren, {Mark R.} and Brayshaw, {Simon K.} and Johnson, {Andrew L.} and Stefanie Schiffers and Raithby, {Paul R.} and Easun, {Timothy L.} and George, {Michael W.} and Warren, {John E.} and Teat, {Simon J.}",

year = "2009",

month = jul,

day = "20",

doi = "10.1002/anie.200901706",

language = "English",

volume = "48",

pages = "5711--5714",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "31",

}

Warren, MR, Brayshaw, SK, Johnson, AL, Schiffers, S, Raithby, PR, Easun, TL, George, MW, Warren, JE & Teat, SJ 2009, 'Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η¹-ONO)C1] isomer', Angewandte Chemie - International Edition, vol. 48, no. 31, pp. 5711-5714. https://doi.org/10.1002/anie.200901706

Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η¹-ONO)C1] isomer. / Warren, Mark R.; Brayshaw, Simon K.; Johnson, Andrew L. et al.
In: Angewandte Chemie - International Edition, Vol. 48, No. 31, 20.07.2009, p. 5711-5714.

Research output: Journal Publication › Article › peer-review

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AU - Warren, John E.

AU - Teat, Simon J.

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