Organometallic alkane and noble-gas complexes in conventional and supercritical fluids

Gavin I. Childs; David C. Grills; Xue Z. Sun; Michael W. George

doi:10.1351/pac200173030443

Organometallic alkane and noble-gas complexes in conventional and supercritical fluids

Gavin I. Childs, David C. Grills, Xue Z. Sun, Michael W. George

Department of Chemical and Environmental Engineering

Research output: Journal Publication › Article › peer-review

38 Citations (Scopus)

Abstract

Fast time-resolved infrared (TRIR) spectroscopy has been used to study a wide range of organometallic alkane and noble-gas complexes at ambient temperature. We have shown that the reactivity of the n-heptane complexes decreases both across and down Groups V, VI, and VII, and that the corresponding xenon complexes have similar reactivities.

Original language	English
Pages (from-to)	443-447
Number of pages	5
Journal	Pure and Applied Chemistry
Volume	73
Issue number	3
DOIs	https://doi.org/10.1351/pac200173030443
Publication status	Published - 2001

ASJC Scopus subject areas

Chemistry (all)
Chemical Engineering (all)

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title = "Organometallic alkane and noble-gas complexes in conventional and supercritical fluids",

abstract = "Fast time-resolved infrared (TRIR) spectroscopy has been used to study a wide range of organometallic alkane and noble-gas complexes at ambient temperature. We have shown that the reactivity of the n-heptane complexes decreases both across and down Groups V, VI, and VII, and that the corresponding xenon complexes have similar reactivities.",

author = "Childs, {Gavin I.} and Grills, {David C.} and Sun, {Xue Z.} and George, {Michael W.}",

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AU - Childs, Gavin I.

AU - Grills, David C.

AU - Sun, Xue Z.

AU - George, Michael W.

PY - 2001

Y1 - 2001

N2 - Fast time-resolved infrared (TRIR) spectroscopy has been used to study a wide range of organometallic alkane and noble-gas complexes at ambient temperature. We have shown that the reactivity of the n-heptane complexes decreases both across and down Groups V, VI, and VII, and that the corresponding xenon complexes have similar reactivities.

AB - Fast time-resolved infrared (TRIR) spectroscopy has been used to study a wide range of organometallic alkane and noble-gas complexes at ambient temperature. We have shown that the reactivity of the n-heptane complexes decreases both across and down Groups V, VI, and VII, and that the corresponding xenon complexes have similar reactivities.

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U2 - 10.1351/pac200173030443

DO - 10.1351/pac200173030443

M3 - Article

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VL - 73

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EP - 447

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

IS - 3

ER -

Organometallic alkane and noble-gas complexes in conventional and supercritical fluids

Abstract

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