Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide

Sihai Yang; Leifeng Liu; Junliang Sun; K. Mark Thomas; Andrew J. Davies; Michael W. George; Alexander J. Blake; Adrian H. Hill; Andrew N. Fitch; Chiu C. Tang; Martin Schröder

doi:10.1021/ja401061m

Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide

Sihai Yang, Leifeng Liu, Junliang Sun, K. Mark Thomas, Andrew J. Davies, Michael W. George, Alexander J. Blake, Adrian H. Hill, Andrew N. Fitch, Chiu C. Tang, Martin Schröder

Research output: Journal Publication › Article › peer-review

125 Citations (Scopus)

Abstract

Porous NOTT-202a shows exceptionally high uptake of SO₂, 13.6 mmol g^-1 (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO₂ uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.

Original language	English
Pages (from-to)	4954-4957
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	13
DOIs	https://doi.org/10.1021/ja401061m
Publication status	Published - 3 Apr 2013
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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Yang, S., Liu, L., Sun, J., Thomas, K. M., Davies, A. J., George, M. W., Blake, A. J., Hill, A. H., Fitch, A. N., Tang, C. C., & Schröder, M. (2013). Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide. Journal of the American Chemical Society, 135(13), 4954-4957. https://doi.org/10.1021/ja401061m

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author = "Sihai Yang and Leifeng Liu and Junliang Sun and Thomas, {K. Mark} and Davies, {Andrew J.} and George, {Michael W.} and Blake, {Alexander J.} and Hill, {Adrian H.} and Fitch, {Andrew N.} and Tang, {Chiu C.} and Martin Schr{\"o}der",

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doi = "10.1021/ja401061m",

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AU - Sun, Junliang

AU - Thomas, K. Mark

AU - Davies, Andrew J.

AU - George, Michael W.

AU - Blake, Alexander J.

AU - Hill, Adrian H.

AU - Fitch, Andrew N.

AU - Tang, Chiu C.

AU - Schröder, Martin

PY - 2013/4/3

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N2 - Porous NOTT-202a shows exceptionally high uptake of SO2, 13.6 mmol g-1 (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO2 uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.

AB - Porous NOTT-202a shows exceptionally high uptake of SO2, 13.6 mmol g-1 (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO2 uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.

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Irreversible network transformation in a dynamic porous host catalyzed by sulfur dioxide

Abstract

ASJC Scopus subject areas

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