Fe-Based Metal-Organic Framework and Its Derivatives for Reversible Lithium Storage

Yan Jin; Chongchong Zhao; Yichao Lin; Deyu Wang; Liang Chen; Cai Shen

doi:10.1016/j.jmst.2016.11.021

Fe-Based Metal-Organic Framework and Its Derivatives for Reversible Lithium Storage

Yan Jin, Chongchong Zhao, Yichao Lin, Deyu Wang, Liang Chen, Cai Shen

Research output: Journal Publication › Article › peer-review

45 Citations (Scopus)

Abstract

The use of a Fe-based metal organic framework (MOF), namely MIL-88B(Fe), as active material for lithium ion batteries (LIBs) is reported for the first time in the present work. Fe-based MOF demonstrated high capacity, excellent cycling stability and rate performance when used as anode. A highly reversible capacity of ~680 mA h g⁻¹ after 500 cycles at a current density of 200 mA g⁻¹ was obtained. In addition, Fe₂O₃ and Fe₃O₄/C composites were obtained from Fe-based MOFs through thermal treatment. Both Fe₂O₃ and Fe₃O₄/C composites demonstrated high capacity and excellent cycling stability.

Original language	English
Pages (from-to)	768-774
Number of pages	7
Journal	Journal of Materials Science and Technology
Volume	33
Issue number	8
DOIs	https://doi.org/10.1016/j.jmst.2016.11.021
Publication status	Published - Aug 2017
Externally published	Yes

Keywords

Anode
Lithium ion battery
Metal organic framework
Metal oxide

ASJC Scopus subject areas

Ceramics and Composites
Mechanics of Materials
Mechanical Engineering
Polymers and Plastics
Metals and Alloys
Materials Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.jmst.2016.11.021

Cite this

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title = "Fe-Based Metal-Organic Framework and Its Derivatives for Reversible Lithium Storage",

abstract = "The use of a Fe-based metal organic framework (MOF), namely MIL-88B(Fe), as active material for lithium ion batteries (LIBs) is reported for the first time in the present work. Fe-based MOF demonstrated high capacity, excellent cycling stability and rate performance when used as anode. A highly reversible capacity of ~680 mA h g−1 after 500 cycles at a current density of 200 mA g−1 was obtained. In addition, Fe2O3 and Fe3O4/C composites were obtained from Fe-based MOFs through thermal treatment. Both Fe2O3 and Fe3O4/C composites demonstrated high capacity and excellent cycling stability.",

keywords = "Anode, Lithium ion battery, Metal organic framework, Metal oxide",

author = "Yan Jin and Chongchong Zhao and Yichao Lin and Deyu Wang and Liang Chen and Cai Shen",

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doi = "10.1016/j.jmst.2016.11.021",

language = "English",

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T1 - Fe-Based Metal-Organic Framework and Its Derivatives for Reversible Lithium Storage

AU - Jin, Yan

AU - Zhao, Chongchong

AU - Lin, Yichao

AU - Wang, Deyu

AU - Chen, Liang

AU - Shen, Cai

PY - 2017/8

Y1 - 2017/8

N2 - The use of a Fe-based metal organic framework (MOF), namely MIL-88B(Fe), as active material for lithium ion batteries (LIBs) is reported for the first time in the present work. Fe-based MOF demonstrated high capacity, excellent cycling stability and rate performance when used as anode. A highly reversible capacity of ~680 mA h g−1 after 500 cycles at a current density of 200 mA g−1 was obtained. In addition, Fe2O3 and Fe3O4/C composites were obtained from Fe-based MOFs through thermal treatment. Both Fe2O3 and Fe3O4/C composites demonstrated high capacity and excellent cycling stability.

AB - The use of a Fe-based metal organic framework (MOF), namely MIL-88B(Fe), as active material for lithium ion batteries (LIBs) is reported for the first time in the present work. Fe-based MOF demonstrated high capacity, excellent cycling stability and rate performance when used as anode. A highly reversible capacity of ~680 mA h g−1 after 500 cycles at a current density of 200 mA g−1 was obtained. In addition, Fe2O3 and Fe3O4/C composites were obtained from Fe-based MOFs through thermal treatment. Both Fe2O3 and Fe3O4/C composites demonstrated high capacity and excellent cycling stability.

KW - Anode

KW - Lithium ion battery

KW - Metal organic framework

KW - Metal oxide

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DO - 10.1016/j.jmst.2016.11.021

M3 - Article

AN - SCOPUS:85007482719

SN - 1005-0302

VL - 33

SP - 768

EP - 774

JO - Journal of Materials Science and Technology

JF - Journal of Materials Science and Technology

IS - 8

ER -

Fe-Based Metal-Organic Framework and Its Derivatives for Reversible Lithium Storage

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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