Transition metal doped CeO₂ for photocatalytic removal of 2-chlorophenol in the exposure of indoor white light and antifungal activity

Besides natural sunlight and expensive artificial lights, economical indoor white light can play a significant role in activating a catalyst for photocatalytic removal of organic toxins from contaminated water. In the current effort, CeO₂ has been modified with Ni, Cu, and Fe through doping methodology to study the removal of 2-chlorophenol (2-CP) in the illumination of 70 W indoor LED white light. The absence of additional diffractions due to the dopants and few changes such as reduction in peaks’ height, minor peak shift at 2θ (28.525°) and peaks’ broadening in XRD patterns of modified CeO₂ verifies the successful doping of CeO₂. The solid-state absorption spectra revealed higher absorbance of Cu-doped CeO₂ whereas a lower absorption response was observed for Ni-doped CeO₂. An interesting observation regarding the lowering of indirect bandgap energy of Fe-doped CeO₂ (∼2.7 eV) and an increase in Ni-doped CeO₂ (∼3.0 eV) in comparison to pristine CeO₂ (∼2.9 eV) was noticed. The process of e^-– h⁺ recombination in the synthesized photocatalysts was also investigated through photoluminescence spectroscopy. The photocatalytic studies revealed the greater photocatalytic activity of Fe-doped CeO₂ with a higher rate (∼3.9 × 10⁻³ min^-1) among all other materials. Moreover, kinetic studies also revealed the validation of the Langmuir-Hinshelwood kinetic model (R² = 0.9839) while removing 2-CP in the exposure of indoor light with a Fe-doped CeO₂ photocatalyst. The XPS analysis revealed the existence of Fe³⁺, Cu²⁺ and Ni²⁺ core levels in doped CeO₂. Using the agar well-diffusion method, the antifungal activity was assessed against the fungus M. fructicola and F. oxysporum. Compared to CeO₂, Ni-doped CeO₂, and Cu-doped CeO₂ nanoparticles, the Fe-doped CeO₂ nanoparticles have outstanding antifungal properties.