Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

Xue Han; Richard A. Bourne; Martyn Poliakoff; Michael W. George

doi:10.1039/b914074c

Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

Xue Han, Richard A. Bourne, Martyn Poliakoff, Michael W. George

Research output: Journal Publication › Article › peer-review

29 Citations (Scopus)

Abstract

Photochemically generated singlet oxygen,¹O₂, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.

Original language	English
Pages (from-to)	1787-1792
Number of pages	6
Journal	Green Chemistry
Volume	11
Issue number	11
DOIs	https://doi.org/10.1039/b914074c
Publication status	Published - 3 Nov 2009
Externally published	Yes

ASJC Scopus subject areas

Environmental Chemistry
Pollution

Access to Document

10.1039/b914074c

Cite this

@article{48fd598ccf4c4615b33214d1ce6ee516,

title = "Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide",

abstract = "Photochemically generated singlet oxygen,1O2, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.",

author = "Xue Han and Bourne, {Richard A.} and Martyn Poliakoff and George, {Michael W.}",

year = "2009",

month = nov,

day = "3",

doi = "10.1039/b914074c",

language = "English",

volume = "11",

pages = "1787--1792",

journal = "Green Chemistry",

issn = "1463-9262",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

AU - Han, Xue

AU - Bourne, Richard A.

AU - Poliakoff, Martyn

AU - George, Michael W.

PY - 2009/11/3

Y1 - 2009/11/3

N2 - Photochemically generated singlet oxygen,1O2, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.

AB - Photochemically generated singlet oxygen,1O2, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.

UR - http://www.scopus.com/inward/record.url?scp=70449371369&partnerID=8YFLogxK

U2 - 10.1039/b914074c

DO - 10.1039/b914074c

M3 - Article

AN - SCOPUS:70449371369

SN - 1463-9262

VL - 11

SP - 1787

EP - 1792

JO - Green Chemistry

JF - Green Chemistry

IS - 11

ER -

Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this