Yang, W., Davies, A. J., Lin, X., Suyetin, M., Matsuda, R., Blake, A. J., Wilson, C., Lewis, W., Parker, J. E., Tang, C. C., George, M. W., Hubberstey, P., Kitagawa, S., Sakamoto, H., Bichoutskaia, E., Champness, N. R., Yang, S., & Schröder, M. (2012). Selective CO 2 uptake and inverse CO 2/C 2H 2 selectivity in a dynamic bifunctional metal-organic framework. Chemical Science, 3(10), 2993-2999. https://doi.org/10.1039/c2sc20443f
Yang, Wenbin ; Davies, Andrew J. ; Lin, Xiang et al. / Selective CO 2 uptake and inverse CO 2/C 2H 2 selectivity in a dynamic bifunctional metal-organic framework. In: Chemical Science. 2012 ; Vol. 3, No. 10. pp. 2993-2999.
@article{2c672244e2334c8f9bf91421b082118d,
title = "Selective CO 2 uptake and inverse CO 2/C 2H 2 selectivity in a dynamic bifunctional metal-organic framework",
abstract = "The unique bifunctional porous metal-organic framework, [Co(HL dc)]·1.5MeOH·dioxane, incorporates both free-standing carboxyl and pyridyl groups within its pores. Gas adsorption measurements on the desolvated framework reveal unusual selective CO 2 adsorption over C 2H 2 and CH 4 linked to a framework phase change from a narrow pore (np) to a large pore (lp) form, mediated by CO 2 uptake at 195 K. This phase transition has been monitored by in situ powder X-ray diffraction and IR spectroscopy, and modelled by Grand Canonical Monte Carlo simulations revealing that the reversible np to lp transition is linked to the rotation of pyridyl rings acting as flexible {"}pore gates{"}.",
author = "Wenbin Yang and Davies, {Andrew J.} and Xiang Lin and Mikhail Suyetin and Ryotaro Matsuda and Blake, {Alexander J.} and Claire Wilson and William Lewis and Parker, {Julia E.} and Tang, {Chiu C.} and George, {Michael W.} and Peter Hubberstey and Susumu Kitagawa and Hirotoshi Sakamoto and Elena Bichoutskaia and Champness, {Neil R.} and Sihai Yang and Martin Schr{\"o}der",
year = "2012",
month = oct,
doi = "10.1039/c2sc20443f",
language = "English",
volume = "3",
pages = "2993--2999",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "10",
}
Yang, W, Davies, AJ, Lin, X, Suyetin, M, Matsuda, R, Blake, AJ, Wilson, C, Lewis, W, Parker, JE, Tang, CC, George, MW, Hubberstey, P, Kitagawa, S, Sakamoto, H, Bichoutskaia, E, Champness, NR, Yang, S & Schröder, M 2012, 'Selective CO 2 uptake and inverse CO 2/C 2H 2 selectivity in a dynamic bifunctional metal-organic framework', Chemical Science, vol. 3, no. 10, pp. 2993-2999. https://doi.org/10.1039/c2sc20443f
Selective CO 2 uptake and inverse CO 2/C 2H 2 selectivity in a dynamic bifunctional metal-organic framework. / Yang, Wenbin; Davies, Andrew J.; Lin, Xiang et al.
In:
Chemical Science, Vol. 3, No. 10, 10.2012, p. 2993-2999.
Research output: Journal Publication › Article › peer-review
TY - JOUR
T1 - Selective CO 2 uptake and inverse CO 2/C 2H 2 selectivity in a dynamic bifunctional metal-organic framework
AU - Yang, Wenbin
AU - Davies, Andrew J.
AU - Lin, Xiang
AU - Suyetin, Mikhail
AU - Matsuda, Ryotaro
AU - Blake, Alexander J.
AU - Wilson, Claire
AU - Lewis, William
AU - Parker, Julia E.
AU - Tang, Chiu C.
AU - George, Michael W.
AU - Hubberstey, Peter
AU - Kitagawa, Susumu
AU - Sakamoto, Hirotoshi
AU - Bichoutskaia, Elena
AU - Champness, Neil R.
AU - Yang, Sihai
AU - Schröder, Martin
PY - 2012/10
Y1 - 2012/10
N2 - The unique bifunctional porous metal-organic framework, [Co(HL dc)]·1.5MeOH·dioxane, incorporates both free-standing carboxyl and pyridyl groups within its pores. Gas adsorption measurements on the desolvated framework reveal unusual selective CO 2 adsorption over C 2H 2 and CH 4 linked to a framework phase change from a narrow pore (np) to a large pore (lp) form, mediated by CO 2 uptake at 195 K. This phase transition has been monitored by in situ powder X-ray diffraction and IR spectroscopy, and modelled by Grand Canonical Monte Carlo simulations revealing that the reversible np to lp transition is linked to the rotation of pyridyl rings acting as flexible "pore gates".
AB - The unique bifunctional porous metal-organic framework, [Co(HL dc)]·1.5MeOH·dioxane, incorporates both free-standing carboxyl and pyridyl groups within its pores. Gas adsorption measurements on the desolvated framework reveal unusual selective CO 2 adsorption over C 2H 2 and CH 4 linked to a framework phase change from a narrow pore (np) to a large pore (lp) form, mediated by CO 2 uptake at 195 K. This phase transition has been monitored by in situ powder X-ray diffraction and IR spectroscopy, and modelled by Grand Canonical Monte Carlo simulations revealing that the reversible np to lp transition is linked to the rotation of pyridyl rings acting as flexible "pore gates".
UR - http://www.scopus.com/inward/record.url?scp=84865766196&partnerID=8YFLogxK
U2 - 10.1039/c2sc20443f
DO - 10.1039/c2sc20443f
M3 - Article
AN - SCOPUS:84865766196
SN - 2041-6520
VL - 3
SP - 2993
EP - 2999
JO - Chemical Science
JF - Chemical Science
IS - 10
ER -
Yang W, Davies AJ, Lin X, Suyetin M, Matsuda R, Blake AJ et al. Selective CO 2 uptake and inverse CO 2/C 2H 2 selectivity in a dynamic bifunctional metal-organic framework. Chemical Science. 2012 Oct;3(10):2993-2999. doi: 10.1039/c2sc20443f
