Abstract
Globally, there is an increasing demand for propylene. Propylene can be produced through the dehydration of bio-isopropanol, which is derived from the fermentation of renewable feedstock. In this study, to enhance the efficiency of the bio-isopropanol-to-propylene (BITP) process, a microwave-sensitive Co3O4@S1/SiC foam catalyst was designed. The performance of the foam catalyst was evaluated across a range of temperatures (50–250 °C) and different heating modes. Investigations revealed that microwave irradiation resulted in a selective formation of propylene of 98.8 %, markedly surpassing the 72.7 % yield achieved with Co3O4@S1/SiC pellets. The exceptional efficiency of the Co3O4@S1/SiC foam in the bio-isopropanol-to-propylene process is predominantly attributable to the enhanced mass and heat transfer facilitated by the well-structured, microwave-sensitive foam SiC. Under microwave irradiation at lower temperatures, this foam catalyst exhibits significantly enhanced efficiency, achieving a 90 % conversion rate at 121 °C, in contrast to the 184 °C required by conventional heating methods to attain a similar rate. Moreover, the synergistic effect between Co3O4 and the second support S1 is crucial, enhancing not only the microwave absorption capacity but also the efficiency of the bio-isopropanol dehydration process.
Original language | English |
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Article number | 141537 |
Journal | Journal of Cleaner Production |
DOIs | |
Publication status | Published - 2 Mar 2024 |
Keywords
- Bio-isopropanol
- Green propylene
- Silicalite-1/SiC foam
- Structured catalyst
- Microwave
- catalystMicrowaveSynergistic effect
ASJC Scopus subject areas
- General Chemical Engineering
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Zhang, J., WANG, C., Lan, D., Liu, Y., Wei, R., Zhu, H., Jiao, Y., Shi, K., Sun, C., & Wu, T. (2024). Rational design of structured Co3O4@silicalite-1/SiC foam catalyst for microwave-assisted highly efficient conversion of bio-isopropanol to green propylene. Journal of Cleaner Production, Article 141537. https://doi.org/10.1016/j.jclepro.2024.141537