Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a PtII diimine chromophore

Julia A. Weinstein; Julia A. Weinstein; Julia A. Weinstein; David C. Grills; Michael Towrie; Pavel Matousek; Anthony W. Parker; Michael W. George

doi:10.1039/b109919a

Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a Pt^II diimine chromophore

Julia A. Weinstein, Julia A. Weinstein, Julia A. Weinstein, David C. Grills, Michael Towrie, Pavel Matousek, Anthony W. Parker, Michael W. George

Research output: Journal Publication › Article › peer-review

27 Citations (Scopus)

Abstract

This is the first report describing the use of picosecond timeresolved infrared (TRIR) spectroscopy to probe a d⁸ metal chromophore, Pt(4,4′-(CO₂Et)₂-2,2′-bpy)Cl₂: monitoring changes in the v(CO) vibrations allows for an assignment of the lowest excited state to an MLCT with an 8.7 ps lifetime.

Original language	English
Pages (from-to)	382-383
Number of pages	2
Journal	Chemical Communications
Volume	4
DOIs	https://doi.org/10.1039/b109919a
Publication status	Published - 21 Feb 2002
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/b109919a

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title = "Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a PtII diimine chromophore",

abstract = "This is the first report describing the use of picosecond timeresolved infrared (TRIR) spectroscopy to probe a d8 metal chromophore, Pt(4,4′-(CO2Et)2-2,2′-bpy)Cl2: monitoring changes in the v(CO) vibrations allows for an assignment of the lowest excited state to an MLCT with an 8.7 ps lifetime.",

author = "Weinstein, {Julia A.} and Weinstein, {Julia A.} and Weinstein, {Julia A.} and Grills, {David C.} and Michael Towrie and Pavel Matousek and Parker, {Anthony W.} and George, {Michael W.}",

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doi = "10.1039/b109919a",

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journal = "Chemical Communications",

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T1 - Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a PtII diimine chromophore

AU - Weinstein, Julia A.

AU - Grills, David C.

AU - Towrie, Michael

AU - Matousek, Pavel

AU - Parker, Anthony W.

AU - George, Michael W.

PY - 2002/2/21

Y1 - 2002/2/21

N2 - This is the first report describing the use of picosecond timeresolved infrared (TRIR) spectroscopy to probe a d8 metal chromophore, Pt(4,4′-(CO2Et)2-2,2′-bpy)Cl2: monitoring changes in the v(CO) vibrations allows for an assignment of the lowest excited state to an MLCT with an 8.7 ps lifetime.

AB - This is the first report describing the use of picosecond timeresolved infrared (TRIR) spectroscopy to probe a d8 metal chromophore, Pt(4,4′-(CO2Et)2-2,2′-bpy)Cl2: monitoring changes in the v(CO) vibrations allows for an assignment of the lowest excited state to an MLCT with an 8.7 ps lifetime.

UR - http://www.scopus.com/inward/record.url?scp=0037148785&partnerID=8YFLogxK

U2 - 10.1039/b109919a

DO - 10.1039/b109919a

M3 - Article

C2 - 12120085

AN - SCOPUS:0037148785

SN - 1359-7345

VL - 4

SP - 382

EP - 383

JO - Chemical Communications

JF - Chemical Communications

ER -

Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a Pt^II diimine chromophore

Abstract

ASJC Scopus subject areas

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