Highly active gauze-supported skeletal nickel catalysts

Kam Loon Fow; Murugan Ganapathi; Ivo Stassen; Jan Fransaer; Koen Binnemans; Dirk E. De Vos

doi:10.1039/c3cc43552k

Highly active gauze-supported skeletal nickel catalysts

Kam Loon Fow, Murugan Ganapathi, Ivo Stassen, Jan Fransaer, Koen Binnemans, Dirk E. De Vos

Research output: Journal Publication › Article › peer-review

12 Citations (Scopus)

Abstract

Gauze-supported skeletal nickel catalysts were prepared by electrodeposition of Ni–Zn alloys from an acetamide–DMSO₂–NiCl₂–ZnCl₂ quaternary melt, followed by chemical or electrochemical leaching of zinc from the alloys. The activity and selectivity of the structured RANEY® nickel surpass those of commercial RANEY® nickel in the hydrogenation of acetophenone.

Original language	English
Pages (from-to)	8498-8500
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	76
DOIs	https://doi.org/10.1039/c3cc43552k
Publication status	Published - 27 Aug 2013
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Highly active gauze-supported skeletal nickel catalysts",

abstract = "Gauze-supported skeletal nickel catalysts were prepared by electrodeposition of Ni–Zn alloys from an acetamide–DMSO2–NiCl2–ZnCl2 quaternary melt, followed by chemical or electrochemical leaching of zinc from the alloys. The activity and selectivity of the structured RANEY{\textregistered} nickel surpass those of commercial RANEY{\textregistered} nickel in the hydrogenation of acetophenone.",

author = "Fow, {Kam Loon} and Murugan Ganapathi and Ivo Stassen and Jan Fransaer and Koen Binnemans and {De Vos}, {Dirk E.}",

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AU - Fow, Kam Loon

AU - Ganapathi, Murugan

AU - Stassen, Ivo

AU - Fransaer, Jan

AU - Binnemans, Koen

AU - De Vos, Dirk E.

PY - 2013/8/27

Y1 - 2013/8/27

N2 - Gauze-supported skeletal nickel catalysts were prepared by electrodeposition of Ni–Zn alloys from an acetamide–DMSO2–NiCl2–ZnCl2 quaternary melt, followed by chemical or electrochemical leaching of zinc from the alloys. The activity and selectivity of the structured RANEY® nickel surpass those of commercial RANEY® nickel in the hydrogenation of acetophenone.

AB - Gauze-supported skeletal nickel catalysts were prepared by electrodeposition of Ni–Zn alloys from an acetamide–DMSO2–NiCl2–ZnCl2 quaternary melt, followed by chemical or electrochemical leaching of zinc from the alloys. The activity and selectivity of the structured RANEY® nickel surpass those of commercial RANEY® nickel in the hydrogenation of acetophenone.

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U2 - 10.1039/c3cc43552k

DO - 10.1039/c3cc43552k

M3 - Article

C2 - 23939339

AN - SCOPUS:84883420966

SN - 1359-7345

VL - 49

SP - 8498

EP - 8500

JO - Chemical Communications

JF - Chemical Communications

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ER -

Highly active gauze-supported skeletal nickel catalysts

Abstract

ASJC Scopus subject areas

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