Green synthesis of chromium-based metal-organic framework (Cr-MOF) from waste polyethylene terephthalate (PET) bottles for hydrogen storage applications

Jianwei Ren; Xoliswa Dyosiba; Nicholas M. Musyoka; Henrietta W. Langmi; Brian C. North; Mkhulu Mathe; Marice S. Onyango

doi:10.1016/j.ijhydene.2016.08.040

Green synthesis of chromium-based metal-organic framework (Cr-MOF) from waste polyethylene terephthalate (PET) bottles for hydrogen storage applications

Jianwei Ren, Xoliswa Dyosiba, Nicholas M. Musyoka, Henrietta W. Langmi, Brian C. North, Mkhulu Mathe, Marice S. Onyango

Research output: Journal Publication › Article › peer-review

127 Citations (Scopus)

Abstract

It is of great economic value to produce high-value PET-based MOF materials by the veritable elimination of waste PET, and provide sufficient MOF materials for hydrogen storage applications. Consequently, this work demonstrates the use of waste PET bottles as direct source of BDC acid linker during the synthesis of Cr-MOF. The PET-derived Cr-MOF materials showed even better textural and hydrogen storage properties than that from commercial BDC (Sigma–Aldrich).

Original language	English
Pages (from-to)	18141-18146
Number of pages	6
Journal	International Journal of Hydrogen Energy
Volume	41
Issue number	40
DOIs	https://doi.org/10.1016/j.ijhydene.2016.08.040
Publication status	Published - 26 Oct 2016
Externally published	Yes

Keywords

Hydrogen storage
Metal-organic frameworks
Polyethylene terephthalate

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Fuel Technology
Condensed Matter Physics
Energy Engineering and Power Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.ijhydene.2016.08.040

Cite this

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title = "Green synthesis of chromium-based metal-organic framework (Cr-MOF) from waste polyethylene terephthalate (PET) bottles for hydrogen storage applications",

abstract = "It is of great economic value to produce high-value PET-based MOF materials by the veritable elimination of waste PET, and provide sufficient MOF materials for hydrogen storage applications. Consequently, this work demonstrates the use of waste PET bottles as direct source of BDC acid linker during the synthesis of Cr-MOF. The PET-derived Cr-MOF materials showed even better textural and hydrogen storage properties than that from commercial BDC (Sigma–Aldrich).",

keywords = "Hydrogen storage, Metal-organic frameworks, Polyethylene terephthalate",

author = "Jianwei Ren and Xoliswa Dyosiba and Musyoka, {Nicholas M.} and Langmi, {Henrietta W.} and North, {Brian C.} and Mkhulu Mathe and Onyango, {Marice S.}",

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year = "2016",

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doi = "10.1016/j.ijhydene.2016.08.040",

language = "English",

volume = "41",

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journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd.",

number = "40",

}

Green synthesis of chromium-based metal-organic framework (Cr-MOF) from waste polyethylene terephthalate (PET) bottles for hydrogen storage applications. / Ren, Jianwei; Dyosiba, Xoliswa; Musyoka, Nicholas M. et al.
In: International Journal of Hydrogen Energy, Vol. 41, No. 40, 26.10.2016, p. 18141-18146.

Research output: Journal Publication › Article › peer-review

TY - JOUR

T1 - Green synthesis of chromium-based metal-organic framework (Cr-MOF) from waste polyethylene terephthalate (PET) bottles for hydrogen storage applications

AU - Ren, Jianwei

AU - Dyosiba, Xoliswa

AU - Musyoka, Nicholas M.

AU - Langmi, Henrietta W.

AU - North, Brian C.

AU - Mathe, Mkhulu

AU - Onyango, Marice S.

PY - 2016/10/26

Y1 - 2016/10/26

N2 - It is of great economic value to produce high-value PET-based MOF materials by the veritable elimination of waste PET, and provide sufficient MOF materials for hydrogen storage applications. Consequently, this work demonstrates the use of waste PET bottles as direct source of BDC acid linker during the synthesis of Cr-MOF. The PET-derived Cr-MOF materials showed even better textural and hydrogen storage properties than that from commercial BDC (Sigma–Aldrich).

AB - It is of great economic value to produce high-value PET-based MOF materials by the veritable elimination of waste PET, and provide sufficient MOF materials for hydrogen storage applications. Consequently, this work demonstrates the use of waste PET bottles as direct source of BDC acid linker during the synthesis of Cr-MOF. The PET-derived Cr-MOF materials showed even better textural and hydrogen storage properties than that from commercial BDC (Sigma–Aldrich).

KW - Hydrogen storage

KW - Metal-organic frameworks

KW - Polyethylene terephthalate

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U2 - 10.1016/j.ijhydene.2016.08.040

DO - 10.1016/j.ijhydene.2016.08.040

M3 - Article

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VL - 41

SP - 18141

EP - 18146

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 40

ER -

Green synthesis of chromium-based metal-organic framework (Cr-MOF) from waste polyethylene terephthalate (PET) bottles for hydrogen storage applications

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

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