Fast time-resolved IR studies of the excited states of co-ordination compound: Direct observation of intramolecular charge transfer

Paul Glyn; Michael W. George; P. Michael Hodges; James J. Turner

doi:10.1039/C39890001655

Fast time-resolved IR studies of the excited states of co-ordination compound: Direct observation of intramolecular charge transfer

Paul Glyn, Michael W. George, P. Michael Hodges, James J. Turner

Research output: Journal Publication › Article › peer-review

64 Citations (Scopus)

Abstract

Fast time-resolved IR (TRIR) spectroscopy is used to record ν(C-O) bands of the lowest lying excited state of [ClRe(CO)₃(4,4′- bipyridyl)₂] (half-life of approximately 1 μs in CH ₂Cl₂ solution); there is a shift of the ν(C-O) bands to higher frequency relative to the ground state, which is consistent with oxidation of the metal centre via electron transfer to the bipyridyl ligands.

Original language	English
Pages (from-to)	1655-1657
Number of pages	3
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39890001655
Publication status	Published - 1989
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39890001655

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title = "Fast time-resolved IR studies of the excited states of co-ordination compound: Direct observation of intramolecular charge transfer",

abstract = "Fast time-resolved IR (TRIR) spectroscopy is used to record ν(C-O) bands of the lowest lying excited state of [ClRe(CO)3(4,4′- bipyridyl)2] (half-life of approximately 1 μs in CH 2Cl2 solution); there is a shift of the ν(C-O) bands to higher frequency relative to the ground state, which is consistent with oxidation of the metal centre via electron transfer to the bipyridyl ligands.",

author = "Paul Glyn and George, {Michael W.} and Hodges, {P. Michael} and Turner, {James J.}",

year = "1989",

doi = "10.1039/C39890001655",

language = "English",

pages = "1655--1657",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "21",

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T1 - Fast time-resolved IR studies of the excited states of co-ordination compound

T2 - Direct observation of intramolecular charge transfer

AU - Glyn, Paul

AU - George, Michael W.

AU - Hodges, P. Michael

AU - Turner, James J.

PY - 1989

Y1 - 1989

N2 - Fast time-resolved IR (TRIR) spectroscopy is used to record ν(C-O) bands of the lowest lying excited state of [ClRe(CO)3(4,4′- bipyridyl)2] (half-life of approximately 1 μs in CH 2Cl2 solution); there is a shift of the ν(C-O) bands to higher frequency relative to the ground state, which is consistent with oxidation of the metal centre via electron transfer to the bipyridyl ligands.

AB - Fast time-resolved IR (TRIR) spectroscopy is used to record ν(C-O) bands of the lowest lying excited state of [ClRe(CO)3(4,4′- bipyridyl)2] (half-life of approximately 1 μs in CH 2Cl2 solution); there is a shift of the ν(C-O) bands to higher frequency relative to the ground state, which is consistent with oxidation of the metal centre via electron transfer to the bipyridyl ligands.

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DO - 10.1039/C39890001655

M3 - Article

AN - SCOPUS:37049074809

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SP - 1655

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JO - Chemical Communications

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ER -

Fast time-resolved IR studies of the excited states of co-ordination compound: Direct observation of intramolecular charge transfer

Abstract

ASJC Scopus subject areas

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