Fabrication of Poly(o-Chloroaniline) to MMT Clay as Potential Flame-Resistant Material

Shahid Iqbal; Sohail Nadeem; Mirza Nadeem Ahmad; Mohsin Javed; Hashem O. Alsaab; Nasser S. Awwad; Hala A. Ibrahium; Eslam B. Elkaeed; Fwzah H. Alshammari; Norah Alwadai; Mohammed Issa Alahmdi; Ali Bahadur; Sadaf ul Hassan; Ayesha Mohyuddin

doi:10.3389/fmats.2022.874735

Fabrication of Poly(o-Chloroaniline) to MMT Clay as Potential Flame-Resistant Material

Shahid Iqbal, Sohail Nadeem, Mirza Nadeem Ahmad, Mohsin Javed, Hashem O. Alsaab, Nasser S. Awwad, Hala A. Ibrahium, Eslam B. Elkaeed, Fwzah H. Alshammari, Norah Alwadai, Mohammed Issa Alahmdi, Ali Bahadur, Sadaf ul Hassan, Ayesha Mohyuddin

Research output: Journal Publication › Article › peer-review

5 Citations (Scopus)

Abstract

Polyorthochloroaniline (POC) nanocomposites with montmorillonite (MMT) clay (POC/MMT) nanocomposites (POC/MMT clay NCs) are the most widespread and attractive among organic/inorganic nanocomposites due to their distinctive properties in addition to inexpensive, abundance, and attractive characteristics such as ion-exchange and great surface area properties and have ample applications. The preparation of polyorthochloroaniline nanocomposites with montmorillonite (POC/MMT) clay nanocomposite has been completed chemically with the help of oxidative polymerization of orthochloroaniline in the presence of montmorillonite (MMT) clay. POC will be admixed with montmorillonite (MMT) clay at various concentrations, by keeping the o-chloroaniline monomer in the reaction mixture constant. To investigate the influence of MMT clay on the characteristics of POC, the load percentage of MMT clay in the nanocomposites was adjusted. The characterization and properties have been determined by using different techniques. FTIR spectroscopy was used to investigate the interactions between POC and MMT. The complete homogeneous dispersion of MMT clay in the POC matrix was examined by scanning electron microscope (SEM) analysis that revealed the compactness. The thermal stability of polymer–clay nanocomposites was determined by thermogravimetric analysis (TGA). The results of DSC/TGA measurements revealed that the flame retardancy and thermal stability of POC/MMT clay nanocomposites were considerably improved.

Original language	English
Article number	874735
Journal	Frontiers in Materials
Volume	9
DOIs	https://doi.org/10.3389/fmats.2022.874735
Publication status	Published - 29 Mar 2022
Externally published	Yes

Keywords

flame retardancy
montmorillonite clay
nanocomposites
nanofiller
polyorthochloroaniline
thermal stability

ASJC Scopus subject areas

Materials Science (miscellaneous)

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10.3389/fmats.2022.874735

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Iqbal, S., Nadeem, S., Ahmad, M. N., Javed, M., Alsaab, H. O., Awwad, N. S., Ibrahium, H. A., Elkaeed, E. B., Alshammari, F. H., Alwadai, N., Alahmdi, M. I., Bahadur, A., Hassan, S. U., & Mohyuddin, A. (2022). Fabrication of Poly(o-Chloroaniline) to MMT Clay as Potential Flame-Resistant Material. Frontiers in Materials, 9, Article 874735. https://doi.org/10.3389/fmats.2022.874735

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title = "Fabrication of Poly(o-Chloroaniline) to MMT Clay as Potential Flame-Resistant Material",

abstract = "Polyorthochloroaniline (POC) nanocomposites with montmorillonite (MMT) clay (POC/MMT) nanocomposites (POC/MMT clay NCs) are the most widespread and attractive among organic/inorganic nanocomposites due to their distinctive properties in addition to inexpensive, abundance, and attractive characteristics such as ion-exchange and great surface area properties and have ample applications. The preparation of polyorthochloroaniline nanocomposites with montmorillonite (POC/MMT) clay nanocomposite has been completed chemically with the help of oxidative polymerization of orthochloroaniline in the presence of montmorillonite (MMT) clay. POC will be admixed with montmorillonite (MMT) clay at various concentrations, by keeping the o-chloroaniline monomer in the reaction mixture constant. To investigate the influence of MMT clay on the characteristics of POC, the load percentage of MMT clay in the nanocomposites was adjusted. The characterization and properties have been determined by using different techniques. FTIR spectroscopy was used to investigate the interactions between POC and MMT. The complete homogeneous dispersion of MMT clay in the POC matrix was examined by scanning electron microscope (SEM) analysis that revealed the compactness. The thermal stability of polymer–clay nanocomposites was determined by thermogravimetric analysis (TGA). The results of DSC/TGA measurements revealed that the flame retardancy and thermal stability of POC/MMT clay nanocomposites were considerably improved.",

keywords = "flame retardancy, montmorillonite clay, nanocomposites, nanofiller, polyorthochloroaniline, thermal stability",

author = "Shahid Iqbal and Sohail Nadeem and Ahmad, {Mirza Nadeem} and Mohsin Javed and Alsaab, {Hashem O.} and Awwad, {Nasser S.} and Ibrahium, {Hala A.} and Elkaeed, {Eslam B.} and Alshammari, {Fwzah H.} and Norah Alwadai and Alahmdi, {Mohammed Issa} and Ali Bahadur and Hassan, {Sadaf ul} and Ayesha Mohyuddin",

note = "Publisher Copyright: Copyright {\textcopyright} 2022 Iqbal, Nadeem, Ahmad, Javed, Alsaab, Awwad, Ibrahium, Elkaeed, Alshammari, Alwadai, Alahmdi, Bahadur, Hassan and Mohyuddin.",

year = "2022",

month = mar,

day = "29",

doi = "10.3389/fmats.2022.874735",

language = "English",

volume = "9",

journal = "Frontiers in Materials",

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T1 - Fabrication of Poly(o-Chloroaniline) to MMT Clay as Potential Flame-Resistant Material

AU - Iqbal, Shahid

AU - Nadeem, Sohail

AU - Ahmad, Mirza Nadeem

AU - Javed, Mohsin

AU - Alsaab, Hashem O.

AU - Awwad, Nasser S.

AU - Ibrahium, Hala A.

AU - Elkaeed, Eslam B.

AU - Alshammari, Fwzah H.

AU - Alwadai, Norah

AU - Alahmdi, Mohammed Issa

AU - Bahadur, Ali

AU - Hassan, Sadaf ul

AU - Mohyuddin, Ayesha

PY - 2022/3/29

Y1 - 2022/3/29

N2 - Polyorthochloroaniline (POC) nanocomposites with montmorillonite (MMT) clay (POC/MMT) nanocomposites (POC/MMT clay NCs) are the most widespread and attractive among organic/inorganic nanocomposites due to their distinctive properties in addition to inexpensive, abundance, and attractive characteristics such as ion-exchange and great surface area properties and have ample applications. The preparation of polyorthochloroaniline nanocomposites with montmorillonite (POC/MMT) clay nanocomposite has been completed chemically with the help of oxidative polymerization of orthochloroaniline in the presence of montmorillonite (MMT) clay. POC will be admixed with montmorillonite (MMT) clay at various concentrations, by keeping the o-chloroaniline monomer in the reaction mixture constant. To investigate the influence of MMT clay on the characteristics of POC, the load percentage of MMT clay in the nanocomposites was adjusted. The characterization and properties have been determined by using different techniques. FTIR spectroscopy was used to investigate the interactions between POC and MMT. The complete homogeneous dispersion of MMT clay in the POC matrix was examined by scanning electron microscope (SEM) analysis that revealed the compactness. The thermal stability of polymer–clay nanocomposites was determined by thermogravimetric analysis (TGA). The results of DSC/TGA measurements revealed that the flame retardancy and thermal stability of POC/MMT clay nanocomposites were considerably improved.

AB - Polyorthochloroaniline (POC) nanocomposites with montmorillonite (MMT) clay (POC/MMT) nanocomposites (POC/MMT clay NCs) are the most widespread and attractive among organic/inorganic nanocomposites due to their distinctive properties in addition to inexpensive, abundance, and attractive characteristics such as ion-exchange and great surface area properties and have ample applications. The preparation of polyorthochloroaniline nanocomposites with montmorillonite (POC/MMT) clay nanocomposite has been completed chemically with the help of oxidative polymerization of orthochloroaniline in the presence of montmorillonite (MMT) clay. POC will be admixed with montmorillonite (MMT) clay at various concentrations, by keeping the o-chloroaniline monomer in the reaction mixture constant. To investigate the influence of MMT clay on the characteristics of POC, the load percentage of MMT clay in the nanocomposites was adjusted. The characterization and properties have been determined by using different techniques. FTIR spectroscopy was used to investigate the interactions between POC and MMT. The complete homogeneous dispersion of MMT clay in the POC matrix was examined by scanning electron microscope (SEM) analysis that revealed the compactness. The thermal stability of polymer–clay nanocomposites was determined by thermogravimetric analysis (TGA). The results of DSC/TGA measurements revealed that the flame retardancy and thermal stability of POC/MMT clay nanocomposites were considerably improved.

KW - flame retardancy

KW - montmorillonite clay

KW - nanocomposites

KW - nanofiller

KW - polyorthochloroaniline

KW - thermal stability

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U2 - 10.3389/fmats.2022.874735

DO - 10.3389/fmats.2022.874735

M3 - Article

AN - SCOPUS:85128419483

SN - 2296-8016

VL - 9

JO - Frontiers in Materials

JF - Frontiers in Materials

M1 - 874735

ER -

Fabrication of Poly(o-Chloroaniline) to MMT Clay as Potential Flame-Resistant Material

Abstract

Keywords

ASJC Scopus subject areas

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