TY - JOUR
T1 - Emerging electrocatalysts for green ammonia production
T2 - Recent progress and future outlook
AU - Mahmood, Sajid
AU - Iqbal, Shahid
AU - Wang, Zeping
AU - Ammar, Muhammad
AU - Iqbal, Muhammad Javed
AU - Bahadur, Ali
AU - Awwad, Nasser S.
AU - Ibrahium, Hala A.
N1 - Publisher Copyright:
© 2024 The Author(s)
PY - 2024/10
Y1 - 2024/10
N2 - In the Haber-Bosch process (HBp), which uses elevated pressure and temperature to produce more concentration of nitrogen and hydrogen gases, 90% of the 175 million metric tons of NH3 generated worldwide in 2016 were manufactured in this process. According to the road plan for sustainable ammonia production sustainably, using water as a reducing agent is the most effective way to fix nitrogen in close-quarters ambiance. A complete explanation of theoretical and practical work on electrocatalytic nitrogen reduction is provided in this article, with special attention paid to the low selectivity of nitrogen reduction to ammonia in comparison to protons to hydrogen. Since they are essential for accurately achieving high nitrogen production and Faradaic efficiency (FE), their information outlines electrocatalysts, electrolyte selection criteria, and managed experiment design. Under diverse conditions, the evolution of theory and experiment is examined. Finally, feedback is given on this field's present issues and prospects.
AB - In the Haber-Bosch process (HBp), which uses elevated pressure and temperature to produce more concentration of nitrogen and hydrogen gases, 90% of the 175 million metric tons of NH3 generated worldwide in 2016 were manufactured in this process. According to the road plan for sustainable ammonia production sustainably, using water as a reducing agent is the most effective way to fix nitrogen in close-quarters ambiance. A complete explanation of theoretical and practical work on electrocatalytic nitrogen reduction is provided in this article, with special attention paid to the low selectivity of nitrogen reduction to ammonia in comparison to protons to hydrogen. Since they are essential for accurately achieving high nitrogen production and Faradaic efficiency (FE), their information outlines electrocatalysts, electrolyte selection criteria, and managed experiment design. Under diverse conditions, the evolution of theory and experiment is examined. Finally, feedback is given on this field's present issues and prospects.
KW - Electrocatalyst
KW - Electrochemical reaction
KW - Faradaic efficiency
KW - Nitrogen production rate
KW - Nitrogen reduction
UR - http://www.scopus.com/inward/record.url?scp=85200809078&partnerID=8YFLogxK
U2 - 10.1016/j.arabjc.2024.105950
DO - 10.1016/j.arabjc.2024.105950
M3 - Review article
AN - SCOPUS:85200809078
SN - 1878-5352
VL - 17
JO - Arabian Journal of Chemistry
JF - Arabian Journal of Chemistry
IS - 10
M1 - 105950
ER -