Effect of organic solvents on solvatochromic, fluorescence, and electrochemical properties of synthesized thiazolylcoumarin derivatives

Ali Bahadur; Shahid Iqbal; Rabail Ujan; Pervaiz Ali Channar; Murefah Mana AL-Anazy; Aamer Saeed; Qaiser Mahmood; Muhammad Shoaib; Mazloom Shah; Ifzan Arshad; Ghulam Shabir; Muhammad Saifullah; Guocong Liu; Muhammad Abdul Qayyum

doi:10.1002/bio.4044

Effect of organic solvents on solvatochromic, fluorescence, and electrochemical properties of synthesized thiazolylcoumarin derivatives

Ali Bahadur, Shahid Iqbal, Rabail Ujan, Pervaiz Ali Channar, Murefah Mana AL-Anazy, Aamer Saeed, Qaiser Mahmood, Muhammad Shoaib, Mazloom Shah, Ifzan Arshad, Ghulam Shabir, Muhammad Saifullah, Guocong Liu, Muhammad Abdul Qayyum

Research output: Journal Publication › Article › peer-review

10 Citations (Scopus)

Abstract

In this present investigation, thiazolylcoumarin derivatives (5a–5k) were synthesized from thiosemicarbazide, ethyl acetoacetate, and naphthaldehyde through a multistep route. The formation of thiazolylcoumarin derivatives with bioactive scaffolds was confirmed through nuclear magnetic resonance spectroscopy. A solvatochromic study of synthesized thiazolylcoumarin derivatives was carried out using ultraviolet–visible methods for dimethylformamide (DMF), ethyl acetate, and ethanol solvents. The redox behaviour of as-synthesized thiazolylcoumarin derivatives (5a–5k) was examined in dimethyl sulphoxide by conducting an electrochemical study. Fluorescence properties of thiazolylcoumarin derivatives were studied in DMF, ethanol, and ethyl acetate to visualize the solvent effect on the emitting ability of thiazolylcoumarin derivatives.

Original language	English
Pages (from-to)	1189-1197
Number of pages	9
Journal	Luminescence
Volume	36
Issue number	5
DOIs	https://doi.org/10.1002/bio.4044
Publication status	Published - Aug 2021
Externally published	Yes

Keywords

fluorescence
solvatochromic study
solvent effect
thiazolylcoumarin derivatives
thiosemicarbazide

ASJC Scopus subject areas

Biophysics
Chemistry (miscellaneous)

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10.1002/bio.4044

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Bahadur, A., Iqbal, S., Ujan, R., Channar, P. A., AL-Anazy, M. M., Saeed, A., Mahmood, Q., Shoaib, M., Shah, M., Arshad, I., Shabir, G., Saifullah, M., Liu, G., & Qayyum, M. A. (2021). Effect of organic solvents on solvatochromic, fluorescence, and electrochemical properties of synthesized thiazolylcoumarin derivatives. Luminescence, 36(5), 1189-1197. https://doi.org/10.1002/bio.4044

@article{7a089cdf2a4441d39e19e0f1548e4d41,

title = "Effect of organic solvents on solvatochromic, fluorescence, and electrochemical properties of synthesized thiazolylcoumarin derivatives",

abstract = "In this present investigation, thiazolylcoumarin derivatives (5a–5k) were synthesized from thiosemicarbazide, ethyl acetoacetate, and naphthaldehyde through a multistep route. The formation of thiazolylcoumarin derivatives with bioactive scaffolds was confirmed through nuclear magnetic resonance spectroscopy. A solvatochromic study of synthesized thiazolylcoumarin derivatives was carried out using ultraviolet–visible methods for dimethylformamide (DMF), ethyl acetate, and ethanol solvents. The redox behaviour of as-synthesized thiazolylcoumarin derivatives (5a–5k) was examined in dimethyl sulphoxide by conducting an electrochemical study. Fluorescence properties of thiazolylcoumarin derivatives were studied in DMF, ethanol, and ethyl acetate to visualize the solvent effect on the emitting ability of thiazolylcoumarin derivatives.",

keywords = "fluorescence, solvatochromic study, solvent effect, thiazolylcoumarin derivatives, thiosemicarbazide",

author = "Ali Bahadur and Shahid Iqbal and Rabail Ujan and Channar, {Pervaiz Ali} and AL-Anazy, {Murefah Mana} and Aamer Saeed and Qaiser Mahmood and Muhammad Shoaib and Mazloom Shah and Ifzan Arshad and Ghulam Shabir and Muhammad Saifullah and Guocong Liu and Qayyum, {Muhammad Abdul}",

note = "Publisher Copyright: {\textcopyright} 2021 John Wiley & Sons Ltd.",

year = "2021",

month = aug,

doi = "10.1002/bio.4044",

language = "English",

volume = "36",

pages = "1189--1197",

journal = "Luminescence",

issn = "1522-7235",

publisher = "John Wiley and Sons Ltd",

number = "5",

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Bahadur, A, Iqbal, S, Ujan, R, Channar, PA, AL-Anazy, MM, Saeed, A, Mahmood, Q, Shoaib, M, Shah, M, Arshad, I, Shabir, G, Saifullah, M, Liu, G & Qayyum, MA 2021, 'Effect of organic solvents on solvatochromic, fluorescence, and electrochemical properties of synthesized thiazolylcoumarin derivatives', Luminescence, vol. 36, no. 5, pp. 1189-1197. https://doi.org/10.1002/bio.4044

TY - JOUR

T1 - Effect of organic solvents on solvatochromic, fluorescence, and electrochemical properties of synthesized thiazolylcoumarin derivatives

AU - Bahadur, Ali

AU - Iqbal, Shahid

AU - Ujan, Rabail

AU - Channar, Pervaiz Ali

AU - AL-Anazy, Murefah Mana

AU - Saeed, Aamer

AU - Mahmood, Qaiser

AU - Shoaib, Muhammad

AU - Shah, Mazloom

AU - Arshad, Ifzan

AU - Shabir, Ghulam

AU - Saifullah, Muhammad

AU - Liu, Guocong

AU - Qayyum, Muhammad Abdul

PY - 2021/8

Y1 - 2021/8

N2 - In this present investigation, thiazolylcoumarin derivatives (5a–5k) were synthesized from thiosemicarbazide, ethyl acetoacetate, and naphthaldehyde through a multistep route. The formation of thiazolylcoumarin derivatives with bioactive scaffolds was confirmed through nuclear magnetic resonance spectroscopy. A solvatochromic study of synthesized thiazolylcoumarin derivatives was carried out using ultraviolet–visible methods for dimethylformamide (DMF), ethyl acetate, and ethanol solvents. The redox behaviour of as-synthesized thiazolylcoumarin derivatives (5a–5k) was examined in dimethyl sulphoxide by conducting an electrochemical study. Fluorescence properties of thiazolylcoumarin derivatives were studied in DMF, ethanol, and ethyl acetate to visualize the solvent effect on the emitting ability of thiazolylcoumarin derivatives.

AB - In this present investigation, thiazolylcoumarin derivatives (5a–5k) were synthesized from thiosemicarbazide, ethyl acetoacetate, and naphthaldehyde through a multistep route. The formation of thiazolylcoumarin derivatives with bioactive scaffolds was confirmed through nuclear magnetic resonance spectroscopy. A solvatochromic study of synthesized thiazolylcoumarin derivatives was carried out using ultraviolet–visible methods for dimethylformamide (DMF), ethyl acetate, and ethanol solvents. The redox behaviour of as-synthesized thiazolylcoumarin derivatives (5a–5k) was examined in dimethyl sulphoxide by conducting an electrochemical study. Fluorescence properties of thiazolylcoumarin derivatives were studied in DMF, ethanol, and ethyl acetate to visualize the solvent effect on the emitting ability of thiazolylcoumarin derivatives.

KW - fluorescence

KW - solvatochromic study

KW - solvent effect

KW - thiazolylcoumarin derivatives

KW - thiosemicarbazide

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U2 - 10.1002/bio.4044

DO - 10.1002/bio.4044

M3 - Article

C2 - 33759314

AN - SCOPUS:85104010889

SN - 1522-7235

VL - 36

SP - 1189

EP - 1197

JO - Luminescence

JF - Luminescence

IS - 5

ER -

Effect of organic solvents on solvatochromic, fluorescence, and electrochemical properties of synthesized thiazolylcoumarin derivatives

Abstract

Keywords

ASJC Scopus subject areas

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