TY - JOUR
T1 - Cellulose beads supported CoFe2O4
T2 - A novel heterogeneous catalyst for efficient rhodamine B degradation via advanced oxidation processes
AU - El Allaoui, Brahim
AU - Benzeid, Hanane
AU - Zari, Nadia
AU - Qaiss, Abou el kacem
AU - Bouhfid, Rachid
N1 - Publisher Copyright:
© 2023 Elsevier B.V.
PY - 2024/2
Y1 - 2024/2
N2 - In this study, a novel mechanical process was used to produce cellulose beads (CB). These beads were then doped with cobalt ferrite nanoparticles (CoFe2O4 NPs) to serve as catalysts for the degradation of rhodamine B (RhB) through peroxymonosulfate (PMS) activation. The physical and chemical properties of CoFe2O4 and CoFe2O4@CB catalysts were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) combined with energy dispersive X-ray spectrometer (EDX), scanning transmission electron microscopy (STEM) techniques, and thermogravimetric analysis (TGA). To optimize RhB degradation efficiency, Response Surface Methodology (RSM) was employed, utilizing the Box-Behnken design (BBD). Under the optimized conditions of a catalyst dosage of 0.40 g/L, PMS dosage of 0.98 mM, RhB concentration of 40 mg/L, pH of 5.27, and reaction time of 60 min, a remarkable degradation efficiency of 98.51 % was achieved at a temperature of 25 °C. In quenching experiments, 1O2, SO4•−, and HO• species are produced in the CoFe2O4@CB/PMS system, with 1O2, and SO4•− species dominating RhB degradation. Remarkably, the new CoFe2O4@CB catalyst has demonstrated exceptional stability and reusability, validated by recycling tests (up to 78 % of RhB degradation efficiency after a 5-cycle experiment) and subsequent characterizations (FTIR, SEM, and EDX) emphasizing unchanged bands, uniform distribution, and consistent composition after reuse cycles. These results demonstrate the effectiveness of mechanically produced CoFe2O4@CB catalysts for advanced oxidation processes (AOPs), with promising applications in wastewater treatment.
AB - In this study, a novel mechanical process was used to produce cellulose beads (CB). These beads were then doped with cobalt ferrite nanoparticles (CoFe2O4 NPs) to serve as catalysts for the degradation of rhodamine B (RhB) through peroxymonosulfate (PMS) activation. The physical and chemical properties of CoFe2O4 and CoFe2O4@CB catalysts were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) combined with energy dispersive X-ray spectrometer (EDX), scanning transmission electron microscopy (STEM) techniques, and thermogravimetric analysis (TGA). To optimize RhB degradation efficiency, Response Surface Methodology (RSM) was employed, utilizing the Box-Behnken design (BBD). Under the optimized conditions of a catalyst dosage of 0.40 g/L, PMS dosage of 0.98 mM, RhB concentration of 40 mg/L, pH of 5.27, and reaction time of 60 min, a remarkable degradation efficiency of 98.51 % was achieved at a temperature of 25 °C. In quenching experiments, 1O2, SO4•−, and HO• species are produced in the CoFe2O4@CB/PMS system, with 1O2, and SO4•− species dominating RhB degradation. Remarkably, the new CoFe2O4@CB catalyst has demonstrated exceptional stability and reusability, validated by recycling tests (up to 78 % of RhB degradation efficiency after a 5-cycle experiment) and subsequent characterizations (FTIR, SEM, and EDX) emphasizing unchanged bands, uniform distribution, and consistent composition after reuse cycles. These results demonstrate the effectiveness of mechanically produced CoFe2O4@CB catalysts for advanced oxidation processes (AOPs), with promising applications in wastewater treatment.
KW - Advanced oxidation process
KW - Cellulose beads
KW - Cobalt ferrite
KW - CoFeO
KW - Peroxymonosulfate
UR - http://www.scopus.com/inward/record.url?scp=85182404918&partnerID=8YFLogxK
U2 - 10.1016/j.ijbiomac.2023.128893
DO - 10.1016/j.ijbiomac.2023.128893
M3 - Article
C2 - 38159693
AN - SCOPUS:85182404918
SN - 0141-8130
VL - 259
JO - International Journal of Biological Macromolecules
JF - International Journal of Biological Macromolecules
M1 - 128893
ER -