Catalytic conversion of bioethanol to value-added chemicals and fuels: A review

Huan Xiang; Ruojia Xin; Natthawan Prasongthum; Paweesuda Natewong; Tawan Sooknoi; Jiawei Wang; Prasert Reubroycharoen; Xiaolei Fan

doi:10.1016/j.recm.2021.12.002

Catalytic conversion of bioethanol to value-added chemicals and fuels: A review

Huan Xiang, Ruojia Xin, Natthawan Prasongthum, Paweesuda Natewong, Tawan Sooknoi, Jiawei Wang, Prasert Reubroycharoen, Xiaolei Fan

Research output: Journal Publication › Review article › peer-review

33 Citations (Scopus)

Abstract

Bioethanol produced via valorisation of renewable biomass is of great interest to many industries. The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions. This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen, C₂–C₄ olefins, gasoline and small oxygenates. Specifically, the focus was placed on the relationship between the catalyst property (such as pore structure, acidity, active metal sites, and catalyst supports) and the catalytic performance (including catalyst activity and stability), as well as the reaction mechanisms involved. Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.

Original language	English
Pages (from-to)	47-68
Number of pages	22
Journal	Resources Chemicals and Materials
Volume	1
Issue number	1
DOIs	https://doi.org/10.1016/j.recm.2021.12.002
Publication status	Published - Mar 2022
Externally published	Yes

Keywords

Bioethanol
Catalysis
Gasoline
Hydrogen, C–C olefins
Oxygenates

ASJC Scopus subject areas

Chemical Engineering (miscellaneous)
Fuel Technology
Materials Science (miscellaneous)

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.recm.2021.12.002

Cite this

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title = "Catalytic conversion of bioethanol to value-added chemicals and fuels: A review",

abstract = "Bioethanol produced via valorisation of renewable biomass is of great interest to many industries. The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions. This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen, C2–C4 olefins, gasoline and small oxygenates. Specifically, the focus was placed on the relationship between the catalyst property (such as pore structure, acidity, active metal sites, and catalyst supports) and the catalytic performance (including catalyst activity and stability), as well as the reaction mechanisms involved. Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.",

keywords = "Bioethanol, Catalysis, Gasoline, Hydrogen, C–C olefins, Oxygenates",

author = "Huan Xiang and Ruojia Xin and Natthawan Prasongthum and Paweesuda Natewong and Tawan Sooknoi and Jiawei Wang and Prasert Reubroycharoen and Xiaolei Fan",

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year = "2022",

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doi = "10.1016/j.recm.2021.12.002",

language = "English",

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TY - JOUR

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T2 - A review

AU - Xiang, Huan

AU - Xin, Ruojia

AU - Prasongthum, Natthawan

AU - Natewong, Paweesuda

AU - Sooknoi, Tawan

AU - Wang, Jiawei

AU - Reubroycharoen, Prasert

AU - Fan, Xiaolei

PY - 2022/3

Y1 - 2022/3

N2 - Bioethanol produced via valorisation of renewable biomass is of great interest to many industries. The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions. This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen, C2–C4 olefins, gasoline and small oxygenates. Specifically, the focus was placed on the relationship between the catalyst property (such as pore structure, acidity, active metal sites, and catalyst supports) and the catalytic performance (including catalyst activity and stability), as well as the reaction mechanisms involved. Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.

AB - Bioethanol produced via valorisation of renewable biomass is of great interest to many industries. The increased availability and decreased cost of bioethanol make it a promising platform molecule to produce a wide range of value-added chemicals and fuels via the catalytic conversions. This paper provides a comprehensive review of catalytic conversions of bioethanol to a variety of chemicals/fuels such as hydrogen, C2–C4 olefins, gasoline and small oxygenates. Specifically, the focus was placed on the relationship between the catalyst property (such as pore structure, acidity, active metal sites, and catalyst supports) and the catalytic performance (including catalyst activity and stability), as well as the reaction mechanisms involved. Future research avenues on the catalyst design for improving catalytic valorisation of bioethanol are also discussed.

KW - Bioethanol

KW - Catalysis

KW - Gasoline

KW - Hydrogen, C–C olefins

KW - Oxygenates

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AN - SCOPUS:85130441686

SN - 2772-4433

VL - 1

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JO - Resources Chemicals and Materials

JF - Resources Chemicals and Materials

IS - 1

ER -

Catalytic conversion of bioethanol to value-added chemicals and fuels: A review

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

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