Ultrafast transient absorption studies of ruthenium and rhenium dipyridophenazine complexes bound to DNA and polynucleotides

C. M. Creely; J. M. Kelly; M. M. Feeney; S. Hudson; J. C. Penedo; W. J. Blau; B. Elias; A. Kirsch-De Mesmaeker; P. Matousek; M. Towrie; A. W. Parker; J. S. Dyer; M. W. George; C. G. Coates; J. J. Mc Garvey

doi:10.1117/12.463625

Ultrafast transient absorption studies of ruthenium and rhenium dipyridophenazine complexes bound to DNA and polynucleotides

C. M. Creely, J. M. Kelly, M. M. Feeney, S. Hudson, J. C. Penedo, W. J. Blau, B. Elias, A. Kirsch-De Mesmaeker, P. Matousek, M. Towrie, A. W. Parker, J. S. Dyer, M. W. George, C. G. Coates, J. J. Mc Garvey

Research output: Journal Publication › Conference article › peer-review

3 Citations (Scopus)

Abstract

We report on ultrafast pump and probe studies of biological systems, in the form of polynucleotide and calf thymus DNA complexes, Molecules for study are bound to the polynucleotides and probed in the visible region to observe changes in the absorption over time. Various dipyridophenazine metal complexes are studied alone and complexed with DNA or synthetic polynucleotides to investigate changes occurring in their excited states upon interacting with nucleobases. Transient absorption measurements are performed pumping at 400nm and probing from 450-700nm with pulse duration of 400fs.

Original language	English
Pages (from-to)	92-102
Number of pages	11
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	4876
Issue number	1
DOIs	https://doi.org/10.1117/12.463625
Publication status	Published - 2002
Externally published	Yes
Event	Opto-Ireland 2002: Optics and Photonics Technologies and Applications - Galway, Ireland Duration: 5 Sept 2002 → 6 Sept 2002

Keywords

DNA complexes
Electron transfer
Metal complexes
Transient absorption
Ultrafast

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

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10.1117/12.463625

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Creely, C. M., Kelly, J. M., Feeney, M. M., Hudson, S., Penedo, J. C., Blau, W. J., Elias, B., Kirsch-De Mesmaeker, A., Matousek, P., Towrie, M., Parker, A. W., Dyer, J. S., George, M. W., Coates, C. G., & Mc Garvey, J. J. (2002). Ultrafast transient absorption studies of ruthenium and rhenium dipyridophenazine complexes bound to DNA and polynucleotides. Proceedings of SPIE - The International Society for Optical Engineering, 4876(1), 92-102. https://doi.org/10.1117/12.463625

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title = "Ultrafast transient absorption studies of ruthenium and rhenium dipyridophenazine complexes bound to DNA and polynucleotides",

abstract = "We report on ultrafast pump and probe studies of biological systems, in the form of polynucleotide and calf thymus DNA complexes, Molecules for study are bound to the polynucleotides and probed in the visible region to observe changes in the absorption over time. Various dipyridophenazine metal complexes are studied alone and complexed with DNA or synthetic polynucleotides to investigate changes occurring in their excited states upon interacting with nucleobases. Transient absorption measurements are performed pumping at 400nm and probing from 450-700nm with pulse duration of 400fs.",

keywords = "DNA complexes, Electron transfer, Metal complexes, Transient absorption, Ultrafast",

author = "Creely, {C. M.} and Kelly, {J. M.} and Feeney, {M. M.} and S. Hudson and Penedo, {J. C.} and Blau, {W. J.} and B. Elias and {Kirsch-De Mesmaeker}, A. and P. Matousek and M. Towrie and Parker, {A. W.} and Dyer, {J. S.} and George, {M. W.} and Coates, {C. G.} and {Mc Garvey}, {J. J.}",

year = "2002",

doi = "10.1117/12.463625",

language = "English",

volume = "4876",

pages = "92--102",

journal = "Proceedings of SPIE - The International Society for Optical Engineering",

issn = "0277-786X",

publisher = "SPIE",

number = "1",

note = "Opto-Ireland 2002: Optics and Photonics Technologies and Applications ; Conference date: 05-09-2002 Through 06-09-2002",

}

Creely, CM, Kelly, JM, Feeney, MM, Hudson, S, Penedo, JC, Blau, WJ, Elias, B, Kirsch-De Mesmaeker, A, Matousek, P, Towrie, M, Parker, AW, Dyer, JS, George, MW, Coates, CG & Mc Garvey, JJ 2002, 'Ultrafast transient absorption studies of ruthenium and rhenium dipyridophenazine complexes bound to DNA and polynucleotides', Proceedings of SPIE - The International Society for Optical Engineering, vol. 4876, no. 1, pp. 92-102. https://doi.org/10.1117/12.463625

TY - JOUR

T1 - Ultrafast transient absorption studies of ruthenium and rhenium dipyridophenazine complexes bound to DNA and polynucleotides

AU - Creely, C. M.

AU - Kelly, J. M.

AU - Feeney, M. M.

AU - Hudson, S.

AU - Penedo, J. C.

AU - Blau, W. J.

AU - Elias, B.

AU - Kirsch-De Mesmaeker, A.

AU - Matousek, P.

AU - Towrie, M.

AU - Parker, A. W.

AU - Dyer, J. S.

AU - George, M. W.

AU - Coates, C. G.

AU - Mc Garvey, J. J.

PY - 2002

Y1 - 2002

N2 - We report on ultrafast pump and probe studies of biological systems, in the form of polynucleotide and calf thymus DNA complexes, Molecules for study are bound to the polynucleotides and probed in the visible region to observe changes in the absorption over time. Various dipyridophenazine metal complexes are studied alone and complexed with DNA or synthetic polynucleotides to investigate changes occurring in their excited states upon interacting with nucleobases. Transient absorption measurements are performed pumping at 400nm and probing from 450-700nm with pulse duration of 400fs.

AB - We report on ultrafast pump and probe studies of biological systems, in the form of polynucleotide and calf thymus DNA complexes, Molecules for study are bound to the polynucleotides and probed in the visible region to observe changes in the absorption over time. Various dipyridophenazine metal complexes are studied alone and complexed with DNA or synthetic polynucleotides to investigate changes occurring in their excited states upon interacting with nucleobases. Transient absorption measurements are performed pumping at 400nm and probing from 450-700nm with pulse duration of 400fs.

KW - DNA complexes

KW - Electron transfer

KW - Metal complexes

KW - Transient absorption

KW - Ultrafast

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U2 - 10.1117/12.463625

DO - 10.1117/12.463625

M3 - Conference article

AN - SCOPUS:0042231078

SN - 0277-786X

VL - 4876

SP - 92

EP - 102

JO - Proceedings of SPIE - The International Society for Optical Engineering

JF - Proceedings of SPIE - The International Society for Optical Engineering

IS - 1

T2 - Opto-Ireland 2002: Optics and Photonics Technologies and Applications

Y2 - 5 September 2002 through 6 September 2002

ER -

Ultrafast transient absorption studies of ruthenium and rhenium dipyridophenazine complexes bound to DNA and polynucleotides

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