Abstract
Laser flash photolysis of [Ru(PPh3)3(CO)(H)2] 1 in benzene solution yielded transient [Ru(PPh3)3(CO)] which was observed by both microsecond UV/VIS and IR spectroscopy [λmax = 380 nm, v(CO) = 1845 cm-1] and reacted with H2 to reform 1 [k2 = (8.4 ± 0.4) × 107 dm3 mol-1 s-1]; photolysis of 1 with an ultrafast laser equipped with IR detection demonstrates that reductive elimination of H2 and formation of [Ru(PPh3)3(CO)] is complete within 6 ps.
Original language | English |
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Pages (from-to) | 2857-2859 |
Number of pages | 3 |
Journal | Journal of the Chemical Society. Dalton Transactions |
Issue number | 17 |
DOIs | |
Publication status | Published - 7 Sept 1997 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry
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Colombo, M., George, M. W., Moore, J. N., Pattison, D. I., Perutz, R. N., Virrels, I. G., & Ye, T. Q. (1997). Ultrafast reductive elimination of hydrogen from a metal carbonyl dihydride complex; a study by time-resolved IR and visible spectroscopy. Journal of the Chemical Society. Dalton Transactions, (17), 2857-2859. https://doi.org/10.1039/a704484d