Two photochemical pathways in competition: Matrix isolation, time- resolved and NMR studies of cis-[Ru(PMe3)4(H)2]

Virginia Montiel-Palma, Robin N. Perutz, Michael W. George, Omar S. Jina, Sylviane Sabo-Etienne

Research output: Journal PublicationArticlepeer-review

22 Citations (Scopus)

Abstract

cis-[Ru(PMe3)4(H)2] (1) reacts by two distinct photochemical pathways resulting in the formation of [Ru(PMe3)4] and [Ru(PMe3)3(H)2]; derivatives of these intermediates are generated in the presence of CO and Ph2SiH2.

Original languageEnglish
Pages (from-to)1175-1176
Number of pages2
JournalChemical Communications
Issue number13
DOIs
Publication statusPublished - 7 Jul 2000
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry (all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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