Transient spectroscopy of dipyridophenazine metal complexes which undergo photo-induced electron transfer with DNA

Jayden A. Smith; Michael W. George; John M. Kelly

doi:10.1016/j.ccr.2011.04.007

Transient spectroscopy of dipyridophenazine metal complexes which undergo photo-induced electron transfer with DNA

Jayden A. Smith, Michael W. George, John M. Kelly

Research output: Journal Publication › Review article › peer-review

61 Citations (Scopus)

Abstract

This review considers transient spectroscopic studies of electron transfer reactions between nucleic acids and the excited states of transition metal complexes containing dipyridophenazine or related ligands and focuses mainly on complexes of ruthenium, chromium and rhenium. Particular emphasis is placed on systems where transient UV/visible and/or infrared absorption spectroscopy have been employed.

Original language	English
Pages (from-to)	2666-2675
Number of pages	10
Journal	Coordination Chemistry Reviews
Volume	255
Issue number	21-22
DOIs	https://doi.org/10.1016/j.ccr.2011.04.007
Publication status	Published - Nov 2011
Externally published	Yes

Keywords

Chromium
DNA
Dipyridophenzine
Dppz
Electron transfer
Metal complexes
Rhenium
Ruthenium
TRIR
Transient spectroscopy

ASJC Scopus subject areas

General Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ccr.2011.04.007

Cite this

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title = "Transient spectroscopy of dipyridophenazine metal complexes which undergo photo-induced electron transfer with DNA",

abstract = "This review considers transient spectroscopic studies of electron transfer reactions between nucleic acids and the excited states of transition metal complexes containing dipyridophenazine or related ligands and focuses mainly on complexes of ruthenium, chromium and rhenium. Particular emphasis is placed on systems where transient UV/visible and/or infrared absorption spectroscopy have been employed.",

keywords = "Chromium, DNA, Dipyridophenzine, Dppz, Electron transfer, Metal complexes, Rhenium, Ruthenium, TRIR, Transient spectroscopy",

author = "Smith, {Jayden A.} and George, {Michael W.} and Kelly, {John M.}",

note = "Funding Information: We thank Ms. Qian Cao, Drs. Xue-Zhong Sun and Tim Easun for helpful discussions. J.A.S. thanks IRCSET for the award of a postdoctoral fellowship. J.M.K.{\textquoteright}s group received financial support from Science Foundation Ireland (grants RFP/06/CHP035 and RFP/06/CHEF437). M.W.G. gratefully acknowledges receipt of a Royal Society Wolfson Merit Award.",

year = "2011",

month = nov,

doi = "10.1016/j.ccr.2011.04.007",

language = "English",

volume = "255",

pages = "2666--2675",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier B.V.",

number = "21-22",

}

TY - JOUR

T1 - Transient spectroscopy of dipyridophenazine metal complexes which undergo photo-induced electron transfer with DNA

AU - Smith, Jayden A.

AU - George, Michael W.

AU - Kelly, John M.

N1 - Funding Information: We thank Ms. Qian Cao, Drs. Xue-Zhong Sun and Tim Easun for helpful discussions. J.A.S. thanks IRCSET for the award of a postdoctoral fellowship. J.M.K.’s group received financial support from Science Foundation Ireland (grants RFP/06/CHP035 and RFP/06/CHEF437). M.W.G. gratefully acknowledges receipt of a Royal Society Wolfson Merit Award.

PY - 2011/11

Y1 - 2011/11

N2 - This review considers transient spectroscopic studies of electron transfer reactions between nucleic acids and the excited states of transition metal complexes containing dipyridophenazine or related ligands and focuses mainly on complexes of ruthenium, chromium and rhenium. Particular emphasis is placed on systems where transient UV/visible and/or infrared absorption spectroscopy have been employed.

AB - This review considers transient spectroscopic studies of electron transfer reactions between nucleic acids and the excited states of transition metal complexes containing dipyridophenazine or related ligands and focuses mainly on complexes of ruthenium, chromium and rhenium. Particular emphasis is placed on systems where transient UV/visible and/or infrared absorption spectroscopy have been employed.

KW - Chromium

KW - DNA

KW - Dipyridophenzine

KW - Dppz

KW - Electron transfer

KW - Metal complexes

KW - Rhenium

KW - Ruthenium

KW - TRIR

KW - Transient spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=80052719287&partnerID=8YFLogxK

U2 - 10.1016/j.ccr.2011.04.007

DO - 10.1016/j.ccr.2011.04.007

M3 - Review article

AN - SCOPUS:80052719287

SN - 0010-8545

VL - 255

SP - 2666

EP - 2675

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - 21-22

ER -

Transient spectroscopy of dipyridophenazine metal complexes which undergo photo-induced electron transfer with DNA

Abstract

Keywords

ASJC Scopus subject areas

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