Transient and Matrix Photochemistry of Fe(dmpe)₂H₂ (dmpe = Me₂PCH₂CH₂PMe₂): Dynamics of C-H and H-H Activation

Keyphrases

• Alkanes 100%
• H Activation 100%
• Arenes 100%
• Et3SiH 100%
• Matrix Photochemistry 100%
• Toluene 50%
• Benzene 50%
• Photochemistry 50%
• Photoproducts 50%
• Photolysis 50%
• Alkane Solvent 50%
• Cyclohexane 50%
• Time-resolved IR Spectroscopy 50%
• Cyclopentane 50%
• Pentane 50%
• Reaction Products 50%
• Methane 50%
• Ambient Temperature 50%
• Ethylene 50%
• Irradiation 50%
• Laser Photolysis 50%
• IR Detection 50%
• UV Detection 50%
• Pulsed Laser 50%
• C-H Bond 50%
• UV Radiation 50%
• Diffusion Control 50%
• Aryl 50%
• Low-temperature Matrices 50%
• Absorption Spectra 50%
• Activation Parameters 50%
• Solution Temperature 50%
• Quencher 50%
• Contrast Reaction 50%
• Second-order Rate Constant 50%
• Pseudo-first-order Rate Constant 50%
• First-row Transition Metal Complexes 50%
• Saturation Kinetics 50%

Chemistry

• Photochemistry 100%
• Photochemical Reaction 100%
• Rate Constant 100%
• Alkane 75%
• Photolysis 50%
• Infrared Spectroscopy 25%
• Cyclohexane 25%
• Pentane 25%
• Methane 25%
• Coordination Compound 25%
• Absorption Spectrum 25%
• Ethylene 25%
• Ultraviolet Irradiation 25%
• Cyclopentene 25%