The characterisation and reactivity of (η5-C5H5)M(CO)3(Xe) (M = Nb or Ta) in solution at room temperature

D. C. Grills, G. I. Childs, M. W. George

Research output: Journal PublicationArticlepeer-review

21 Citations (Scopus)

Abstract

Employing fast time-resolved infrared (TRIR) spectroscopy we have characterised CpM(CO)3(Xe) (M = Nb or Ta) at room temperature in supercritical Xe solution; CpM(CO)3(Xe) were found to exhibit a similar reactivity with CO to the corresponding alkane complexes, CpM(CO)3(n-heptane) and we report a trend in reactivity of the early transition metal Xe complexes.

Original languageEnglish
Pages (from-to)1841-1842
Number of pages2
JournalChemical Communications
Issue number19
DOIs
Publication statusPublished - 7 Oct 2000
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry (all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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