The characterisation and reactivity of (η5-C5H5)M(CO)3(Xe) (M = Nb or Ta) in solution at room temperature

D. C. Grills; G. I. Childs; M. W. George

doi:10.1039/b004843g

The characterisation and reactivity of (η⁵-C₅H₅)M(CO)₃(Xe) (M = Nb or Ta) in solution at room temperature

D. C. Grills, G. I. Childs, M. W. George

Research output: Journal Publication › Article › peer-review

23 Citations (Scopus)

Abstract

Employing fast time-resolved infrared (TRIR) spectroscopy we have characterised CpM(CO)₃(Xe) (M = Nb or Ta) at room temperature in supercritical Xe solution; CpM(CO)₃(Xe) were found to exhibit a similar reactivity with CO to the corresponding alkane complexes, CpM(CO)₃(n-heptane) and we report a trend in reactivity of the early transition metal Xe complexes.

Original language	English
Pages (from-to)	1841-1842
Number of pages	2
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/b004843g
Publication status	Published - 7 Oct 2000
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Employing fast time-resolved infrared (TRIR) spectroscopy we have characterised CpM(CO)3(Xe) (M = Nb or Ta) at room temperature in supercritical Xe solution; CpM(CO)3(Xe) were found to exhibit a similar reactivity with CO to the corresponding alkane complexes, CpM(CO)3(n-heptane) and we report a trend in reactivity of the early transition metal Xe complexes.",

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AU - Childs, G. I.

AU - George, M. W.

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Y1 - 2000/10/7

N2 - Employing fast time-resolved infrared (TRIR) spectroscopy we have characterised CpM(CO)3(Xe) (M = Nb or Ta) at room temperature in supercritical Xe solution; CpM(CO)3(Xe) were found to exhibit a similar reactivity with CO to the corresponding alkane complexes, CpM(CO)3(n-heptane) and we report a trend in reactivity of the early transition metal Xe complexes.

AB - Employing fast time-resolved infrared (TRIR) spectroscopy we have characterised CpM(CO)3(Xe) (M = Nb or Ta) at room temperature in supercritical Xe solution; CpM(CO)3(Xe) were found to exhibit a similar reactivity with CO to the corresponding alkane complexes, CpM(CO)3(n-heptane) and we report a trend in reactivity of the early transition metal Xe complexes.

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The characterisation and reactivity of (η⁵-C₅H₅)M(CO)₃(Xe) (M = Nb or Ta) in solution at room temperature

Abstract

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