Supramolecular structure of A- and B-type granules of wheat starch

Binjia Zhang, Xiaoxi Li, Jia Liu, Fengwei Xie, Ling Chen

Research output: Journal PublicationArticlepeer-review

290 Citations (Scopus)

Abstract

The supramolecular structure of the A- and B-type granules of wheat starch was compared. Polarized light microscopy, X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR) were used to study the granular, crystalline, and short-range structures. The A- and B-type granules displayed a typical A-type crystalline structure with the degrees of crystallinity of 31.95% and 29.38% respectively. In addition, the B-type granules had some V-type crystallites. The nanostructure and fractals were characterized by small angle X-ray scattering (SAXS), which showed that the average thickness of the lamellae of the A-type granules was larger, while the B-type granules possessed a higher degree of ordering in the lamellar regions. A second order reflection was found in both A- and B-type granules, which was proposed due to the crystalline lamellae of the semicrystalline lamellae. The A- and B-type granules had mass and surface fractal structures respectively.

Original languageEnglish
Pages (from-to)68-73
Number of pages6
JournalFood Hydrocolloids
Volume31
Issue number1
DOIs
Publication statusPublished - 2013
Externally publishedYes

Keywords

  • A-type granule
  • B-type granule
  • Crystalline structure
  • Fractal
  • Nanostructure
  • Wheat starch

ASJC Scopus subject areas

  • Food Science
  • General Chemistry
  • General Chemical Engineering

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