Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

Mark R. Warren, Simon K. Brayshaw, Andrew L. Johnson, Stefanie Schiffers, Paul R. Raithby, Timothy L. Easun, Michael W. George, John E. Warren, Simon J. Teat

Research output: Journal PublicationArticlepeer-review

69 Citations (Scopus)

Abstract

Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer.

Original languageEnglish
Pages (from-to)5711-5714
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number31
DOIs
Publication statusPublished - 20 Jul 2009
Externally publishedYes

Keywords

  • Linkage isomerism
  • Metastable compounds
  • Nitrites
  • Photocrystallography
  • Raman spectroscopy

ASJC Scopus subject areas

  • Catalysis
  • Chemistry (all)

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