Abstract
Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer.
Original language | English |
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Pages (from-to) | 5711-5714 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 48 |
Issue number | 31 |
DOIs | |
Publication status | Published - 20 Jul 2009 |
Externally published | Yes |
Keywords
- Linkage isomerism
- Metastable compounds
- Nitrites
- Photocrystallography
- Raman spectroscopy
ASJC Scopus subject areas
- Catalysis
- General Chemistry