Removal of heavy metals by covalent organic frameworks (COFs): A review on its mechanism and adsorption properties

Eman A. Gendy, Jerosha Ifthikar, Jawad Ali, Daniel T. Oyekunle, Zouhair Elkhlifia, Irshad Ibran Shahib, Ahmed I. Khodair, Zhuqi Chen

Research output: Journal PublicationReview articlepeer-review

112 Citations (Scopus)

Abstract

Covalent organic frameworks (COFs) have demonstrated a great potential in the removal of heavy metals due to its high adsorption capacity, large surface area, tunable porosity, porous structure, and recyclability. These features give COFs advantages over traditional adsorbents. The occurrence of heavy metals in surface and groundwater above the maximum acceptable limit poses a great threat not only for human health but also for the environment. The elimination of these large amounts of heavy metals serves as a significant challenge. Hence, this review complies the recent investigations on COFs as a superior material in the removal of heavy metals from water considering various environmental parameters as well as the recycling process using different regeneration agents. The selectivity and sensitivity of COFs and COF-based materials were elucidated. Moreover, the different adsorption mechanisms of heavy metals by COF-based materials are critically discussed. The chemical structures and functional groups play a significant role in enhancing the removal efficiency of heavy metals. In addition, personal insights based on the interaction mechanism of COFs and various functional groups into future research prospects. We believe that this review paper can motivate more researchers to use COFs for water remediation.

Original languageEnglish
Article number105687
JournalJournal of Environmental Chemical Engineering
Volume9
Issue number4
DOIs
Publication statusPublished - Aug 2021

Keywords

  • Adsorption mechanism
  • Covalent organic frameworks
  • Heavy metals

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Waste Management and Disposal
  • Pollution
  • Process Chemistry and Technology

Fingerprint

Dive into the research topics of 'Removal of heavy metals by covalent organic frameworks (COFs): A review on its mechanism and adsorption properties'. Together they form a unique fingerprint.

Cite this