Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)- (pyridinato-C,3N') ligand: Nature and dynamics of the lowest excited state of the chloro- And thiolato-complexes

Yurii A. Kovelenov; Alexander J. Blake; Michael W. George; Pavel Matousek; Mikhail Ya Mel'Nikov; Anthony W. Parker; Xue Zhong Sun; Michael Towrie; Julia A. Weinstein

doi:10.1039/b502375k

Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)- (pyridinato-C,³N') ligand: Nature and dynamics of the lowest excited state of the chloro- And thiolato-complexes

Yurii A. Kovelenov, Alexander J. Blake, Michael W. George, Pavel Matousek, Mikhail Ya Mel'Nikov, Anthony W. Parker, Xue Zhong Sun, Michael Towrie, Julia A. Weinstein

Research output: Journal Publication › Article › peer-review

13 Citations (Scopus)

Abstract

The synthesis of a cyclometallated Pt(II) thiolate carbonyl complex Pt(thpy)(CO)(mts), (thpy = 2-(2'-thienyl)-pyridinate, mts = methylthiosalicylate) is reported. A combination of emission and time-resolved infrared (TRIR) techniques revealed for both Pt(thpy)(CO)(mts) and its chloride analogue Pt(thpy)(CO)Cl the predominant intra 2-(2'-thienyl)-pyridinate ³ππ* character of the lowest electronic excited state. The unusually short lifetime (780 ps) of the intraligand ³ππ * lowest excited state of Pt(thpy)(CO)(mts) indicates that this electronic state is influenced by another close-lying excited state, probably charge-transfer in origin.

Original language	English
Pages (from-to)	2092-2097
Number of pages	6
Journal	Dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/b502375k
Publication status	Published - 21 Jun 2005
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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Kovelenov, Y. A., Blake, A. J., George, M. W., Matousek, P., Mel'Nikov, M. Y., Parker, A. W., Sun, X. Z., Towrie, M., & Weinstein, J. A. (2005). Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)- (pyridinato-C,³N') ligand: Nature and dynamics of the lowest excited state of the chloro- And thiolato-complexes. Dalton Transactions, (12), 2092-2097. https://doi.org/10.1039/b502375k

@article{d1daceb067344ceeb999c1329ce81293,

title = "Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)- (pyridinato-C,3N') ligand: Nature and dynamics of the lowest excited state of the chloro- And thiolato-complexes",

abstract = "The synthesis of a cyclometallated Pt(II) thiolate carbonyl complex Pt(thpy)(CO)(mts), (thpy = 2-(2'-thienyl)-pyridinate, mts = methylthiosalicylate) is reported. A combination of emission and time-resolved infrared (TRIR) techniques revealed for both Pt(thpy)(CO)(mts) and its chloride analogue Pt(thpy)(CO)Cl the predominant intra 2-(2'-thienyl)-pyridinate 3ππ* character of the lowest electronic excited state. The unusually short lifetime (780 ps) of the intraligand 3ππ * lowest excited state of Pt(thpy)(CO)(mts) indicates that this electronic state is influenced by another close-lying excited state, probably charge-transfer in origin.",

author = "Kovelenov, {Yurii A.} and Blake, {Alexander J.} and George, {Michael W.} and Pavel Matousek and Mel'Nikov, {Mikhail Ya} and Parker, {Anthony W.} and Sun, {Xue Zhong} and Michael Towrie and Weinstein, {Julia A.}",

year = "2005",

month = jun,

day = "21",

doi = "10.1039/b502375k",

language = "English",

pages = "2092--2097",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "12",

}

Kovelenov, YA, Blake, AJ, George, MW, Matousek, P, Mel'Nikov, MY, Parker, AW, Sun, XZ, Towrie, M & Weinstein, JA 2005, 'Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)- (pyridinato-C,³N') ligand: Nature and dynamics of the lowest excited state of the chloro- And thiolato-complexes', Dalton Transactions, no. 12, pp. 2092-2097. https://doi.org/10.1039/b502375k

Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)- (pyridinato-C,³N') ligand: Nature and dynamics of the lowest excited state of the chloro- And thiolato-complexes. / Kovelenov, Yurii A.; Blake, Alexander J.; George, Michael W. et al.
In: Dalton Transactions, No. 12, 21.06.2005, p. 2092-2097.

Research output: Journal Publication › Article › peer-review

TY - JOUR

T1 - Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)- (pyridinato-C,3N') ligand

T2 - Nature and dynamics of the lowest excited state of the chloro- And thiolato-complexes

AU - Kovelenov, Yurii A.

AU - Blake, Alexander J.

AU - George, Michael W.

AU - Matousek, Pavel

AU - Mel'Nikov, Mikhail Ya

AU - Parker, Anthony W.

AU - Sun, Xue Zhong

AU - Towrie, Michael

AU - Weinstein, Julia A.

PY - 2005/6/21

Y1 - 2005/6/21

N2 - The synthesis of a cyclometallated Pt(II) thiolate carbonyl complex Pt(thpy)(CO)(mts), (thpy = 2-(2'-thienyl)-pyridinate, mts = methylthiosalicylate) is reported. A combination of emission and time-resolved infrared (TRIR) techniques revealed for both Pt(thpy)(CO)(mts) and its chloride analogue Pt(thpy)(CO)Cl the predominant intra 2-(2'-thienyl)-pyridinate 3ππ* character of the lowest electronic excited state. The unusually short lifetime (780 ps) of the intraligand 3ππ * lowest excited state of Pt(thpy)(CO)(mts) indicates that this electronic state is influenced by another close-lying excited state, probably charge-transfer in origin.

AB - The synthesis of a cyclometallated Pt(II) thiolate carbonyl complex Pt(thpy)(CO)(mts), (thpy = 2-(2'-thienyl)-pyridinate, mts = methylthiosalicylate) is reported. A combination of emission and time-resolved infrared (TRIR) techniques revealed for both Pt(thpy)(CO)(mts) and its chloride analogue Pt(thpy)(CO)Cl the predominant intra 2-(2'-thienyl)-pyridinate 3ππ* character of the lowest electronic excited state. The unusually short lifetime (780 ps) of the intraligand 3ππ * lowest excited state of Pt(thpy)(CO)(mts) indicates that this electronic state is influenced by another close-lying excited state, probably charge-transfer in origin.

UR - http://www.scopus.com/inward/record.url?scp=21344457888&partnerID=8YFLogxK

U2 - 10.1039/b502375k

DO - 10.1039/b502375k

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SN - 1477-9226

SP - 2092

EP - 2097

JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)- (pyridinato-C,³N') ligand: Nature and dynamics of the lowest excited state of the chloro- And thiolato-complexes

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