Photochemistry of 2-(methoxycarbonyl)phenyl azide in solution at room temperature: A time-resolved infrared study

Xue Zhong Sun; Ian G. Virrels; Michael W. George; Hideo Tomioka

doi:10.1246/cl.1996.1089

Photochemistry of 2-(methoxycarbonyl)phenyl azide in solution at room temperature: A time-resolved infrared study

Xue Zhong Sun, Ian G. Virrels, Michael W. George, Hideo Tomioka

Research output: Journal Publication › Article › peer-review

13 Citations (Scopus)

Abstract

Time-resolved infrared studies of intermediates generated by photolysis of the title azide in solution at room temperature demonstrated that 3-(methoxycarbonyl)azacycloheptatetraene was the sole intermediate at least in the μs time scale, which is in sharp contrast with that observed in the photolysis in argon matrix at 10 K. Substituent effects on the reactivity of the dehydroazepine toward diethylamine are also discussed.

Original language	English
Pages (from-to)	1089-1090
Number of pages	2
Journal	Chemistry Letters
Issue number	12
DOIs	https://doi.org/10.1246/cl.1996.1089
Publication status	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.1996.1089

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title = "Photochemistry of 2-(methoxycarbonyl)phenyl azide in solution at room temperature: A time-resolved infrared study",

abstract = "Time-resolved infrared studies of intermediates generated by photolysis of the title azide in solution at room temperature demonstrated that 3-(methoxycarbonyl)azacycloheptatetraene was the sole intermediate at least in the μs time scale, which is in sharp contrast with that observed in the photolysis in argon matrix at 10 K. Substituent effects on the reactivity of the dehydroazepine toward diethylamine are also discussed.",

author = "Sun, {Xue Zhong} and Virrels, {Ian G.} and George, {Michael W.} and Hideo Tomioka",

year = "1996",

doi = "10.1246/cl.1996.1089",

language = "English",

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journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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T1 - Photochemistry of 2-(methoxycarbonyl)phenyl azide in solution at room temperature

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AU - Sun, Xue Zhong

AU - Virrels, Ian G.

AU - George, Michael W.

AU - Tomioka, Hideo

PY - 1996

Y1 - 1996

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AB - Time-resolved infrared studies of intermediates generated by photolysis of the title azide in solution at room temperature demonstrated that 3-(methoxycarbonyl)azacycloheptatetraene was the sole intermediate at least in the μs time scale, which is in sharp contrast with that observed in the photolysis in argon matrix at 10 K. Substituent effects on the reactivity of the dehydroazepine toward diethylamine are also discussed.

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DO - 10.1246/cl.1996.1089

M3 - Article

AN - SCOPUS:0004468912

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 12

ER -

Photochemistry of 2-(methoxycarbonyl)phenyl azide in solution at room temperature: A time-resolved infrared study

Abstract

ASJC Scopus subject areas

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