Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Inès G.T.M. Penders; Zacharias Amara; Raphael Horvath; Kai Rossen; Martyn Poliakoff; Michael W. George

doi:10.1039/c4ra15588b

Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Inès G.T.M. Penders, Zacharias Amara, Raphael Horvath, Kai Rossen, Martyn Poliakoff, Michael W. George

Department of Chemical and Environmental Engineering

Research output: Journal Publication › Article › peer-review

35 Citations (Scopus)

Abstract

The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H₂O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.

Original language	English
Pages (from-to)	6501-6504
Number of pages	4
Journal	RSC Advances
Volume	5
Issue number	9
DOIs	https://doi.org/10.1039/c4ra15588b
Publication status	Published - 2015

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1039/c4ra15588b

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title = "Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors",

abstract = "The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.",

author = "Penders, {In{\`e}s G.T.M.} and Zacharias Amara and Raphael Horvath and Kai Rossen and Martyn Poliakoff and George, {Michael W.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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AU - Penders, Inès G.T.M.

AU - Amara, Zacharias

AU - Horvath, Raphael

AU - Rossen, Kai

AU - Poliakoff, Martyn

AU - George, Michael W.

PY - 2015

Y1 - 2015

N2 - The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.

AB - The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH-H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.

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U2 - 10.1039/c4ra15588b

DO - 10.1039/c4ra15588b

M3 - Article

AN - SCOPUS:84920860813

SN - 2046-2069

VL - 5

SP - 6501

EP - 6504

JO - RSC Advances

JF - RSC Advances

IS - 9

ER -

Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Abstract

ASJC Scopus subject areas

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