Phase separation time/temperature dependence of some thermoplastics- modified thermosetting systems

Xiujuan Zhang; Xiaosu Yi; Yuanze Xu

doi:10.1007/s11458-008-0056-6

Phase separation time/temperature dependence of some thermoplastics- modified thermosetting systems

Xiujuan Zhang, Xiaosu Yi, Yuanze Xu

Research output: Journal Publication › Article › peer-review

3 Citations (Scopus)

Abstract

The phase separation processes of various thermoplastics-modified thermosetting systems which show upper critical solution temperature (UCST) or lower critical solution temperature (LCST) were studied with emphasis on the temperature dependency of the phase separation times. It was found that the phase separation time-temperature relationship follows the Arrhenius equation. The cure-induced phase separation activation energy E _a (ps) generated from the equation is independent of the method used to measure phase separation time. In our experimental ranges it is found that E _a (ps) is independent of the thermoplastic (TP) content, TP molecular weight and curing rate but it varies with the cure reaction kinetics and the chemical environments of the systems.

Original language	English
Pages (from-to)	471-479
Number of pages	9
Journal	Frontiers of Chemistry in China
Volume	3
Issue number	4
DOIs	https://doi.org/10.1007/s11458-008-0056-6
Publication status	Published - Dec 2008
Externally published	Yes

Keywords

Arrhenius equation
Polymerization induced phase separation
Thermoplastic
Thermosetting
Time and temperature dependence

ASJC Scopus subject areas

General Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1007/s11458-008-0056-6

Cite this

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title = "Phase separation time/temperature dependence of some thermoplastics- modified thermosetting systems",

abstract = "The phase separation processes of various thermoplastics-modified thermosetting systems which show upper critical solution temperature (UCST) or lower critical solution temperature (LCST) were studied with emphasis on the temperature dependency of the phase separation times. It was found that the phase separation time-temperature relationship follows the Arrhenius equation. The cure-induced phase separation activation energy E a (ps) generated from the equation is independent of the method used to measure phase separation time. In our experimental ranges it is found that E a (ps) is independent of the thermoplastic (TP) content, TP molecular weight and curing rate but it varies with the cure reaction kinetics and the chemical environments of the systems.",

keywords = "Arrhenius equation, Polymerization induced phase separation, Thermoplastic, Thermosetting, Time and temperature dependence",

author = "Xiujuan Zhang and Xiaosu Yi and Yuanze Xu",

year = "2008",

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doi = "10.1007/s11458-008-0056-6",

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T1 - Phase separation time/temperature dependence of some thermoplastics- modified thermosetting systems

AU - Zhang, Xiujuan

AU - Yi, Xiaosu

AU - Xu, Yuanze

PY - 2008/12

Y1 - 2008/12

N2 - The phase separation processes of various thermoplastics-modified thermosetting systems which show upper critical solution temperature (UCST) or lower critical solution temperature (LCST) were studied with emphasis on the temperature dependency of the phase separation times. It was found that the phase separation time-temperature relationship follows the Arrhenius equation. The cure-induced phase separation activation energy E a (ps) generated from the equation is independent of the method used to measure phase separation time. In our experimental ranges it is found that E a (ps) is independent of the thermoplastic (TP) content, TP molecular weight and curing rate but it varies with the cure reaction kinetics and the chemical environments of the systems.

AB - The phase separation processes of various thermoplastics-modified thermosetting systems which show upper critical solution temperature (UCST) or lower critical solution temperature (LCST) were studied with emphasis on the temperature dependency of the phase separation times. It was found that the phase separation time-temperature relationship follows the Arrhenius equation. The cure-induced phase separation activation energy E a (ps) generated from the equation is independent of the method used to measure phase separation time. In our experimental ranges it is found that E a (ps) is independent of the thermoplastic (TP) content, TP molecular weight and curing rate but it varies with the cure reaction kinetics and the chemical environments of the systems.

KW - Arrhenius equation

KW - Polymerization induced phase separation

KW - Thermoplastic

KW - Thermosetting

KW - Time and temperature dependence

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M3 - Article

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SN - 1673-3495

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JF - Frontiers of Chemistry in China

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ER -

Phase separation time/temperature dependence of some thermoplastics- modified thermosetting systems

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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