Nitrogen doped hollow carbon nanospheres as efficient polysulfide restricted layer on commercial separators for high-performance lithium-sulfur batteries

Yue Zhao, Zhi GU, Wei Weng, Dan Zhou, Ziqiang Liu, Wentong Fan, Shungui Deng, Hao He, Xiayin Yao

Research output: Journal PublicationArticlepeer-review

18 Citations (Scopus)

Abstract

The polysulfide shuttle limits the development of lithium-sulfur (Li-S) batteries with high energy density and long lifespan. Herein, nitrogen doped hollow carbon nanospheres (NHCS) derived from polymerization of dopamine on SiO2 nanospheres are employed to modify the commercial polypropylene/polyethylene/polypropylene tri-layer separators (PP/PE/PP@NHCS). The abundant nitrogen heteroatoms in NHCS exhibit strong chemical adsorption toward polysulfides, which can effectively suppress the lithium polysulfides shuttle and further enhance the utilization of active sulfur. Lithium-sulfur batteries employing the PP/PE/PP@NHCS deliver an initial discharge capacity of 1355 mAh/g and retain high capacity of 921 mAh/g after 100 cycles at 0.2 C. At a high rate of 2 C, the lithium-sulfur batteries exhibit capacity of 461 mAh/g after 1000 cycles with a capacity fading rate of 0.049% per cycle. This work demonstrates that the NHCS coated PP/PE/PP separator is promising for future commercial applications of lithium-sulfur batteries with improved electrochemical performances.
Original languageEnglish
Article number107232
JournalChinese Chemical Letters
Volume34
Issue number2
DOIs
Publication statusPublished - Feb 2023

Keywords

  • Nitrogen doped hollow carbon nanospheres
  • Separator modification
  • Shuffle effect
  • Polysulfides
  • Lithium-sulfur batteries

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