Abstract
UV photolysis of CpMn(CO)3 (Cp = C5H5) in near critical liquid N2O at room temperature in both static and flow reactors leads to the formation of CpMn(CO)2(N2O) identified via ν(C-O) and ν(N2O) IR bands, the latter being recorded in low temperature polyethylene (PE) experiments. CpMn(CO)2(N2O) has a lifetime of ca. 5 min at room temperature in near-critical N2O and appears to have two decay pathways one of which leads to CpMn(CO)2(N2), possibly via O-transfer.
Original language | English |
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Pages (from-to) | 1260-1261 |
Number of pages | 2 |
Journal | Chemistry Letters |
Issue number | 11 |
DOIs | |
Publication status | Published - 2000 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry