IR evidence for the generation of (C5H5)Mn(CO)2(N2O) in near-critical N2O at room temperature and in polyethylene matrices at low temperature

Karine Molvinger; Gavin I. Childs; Margaret Jobling; Mark Roper; Michael W. George; Martyn Poliakoff

doi:10.1246/cl.2000.1260

IR evidence for the generation of (C₅H₅)Mn(CO)₂(N₂O) in near-critical N₂O at room temperature and in polyethylene matrices at low temperature

Karine Molvinger, Gavin I. Childs, Margaret Jobling, Mark Roper, Michael W. George, Martyn Poliakoff

Research output: Journal Publication › Article › peer-review

6 Citations (Scopus)

Abstract

UV photolysis of CpMn(CO)₃ (Cp = C₅H₅) in near critical liquid N₂O at room temperature in both static and flow reactors leads to the formation of CpMn(CO)₂(N₂O) identified via ν(C-O) and ν(N₂O) IR bands, the latter being recorded in low temperature polyethylene (PE) experiments. CpMn(CO)₂(N₂O) has a lifetime of ca. 5 min at room temperature in near-critical N₂O and appears to have two decay pathways one of which leads to CpMn(CO)₂(N₂), possibly via O-transfer.

Original language	English
Pages (from-to)	1260-1261
Number of pages	2
Journal	Chemistry Letters
Issue number	11
DOIs	https://doi.org/10.1246/cl.2000.1260
Publication status	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "IR evidence for the generation of (C5H5)Mn(CO)2(N2O) in near-critical N2O at room temperature and in polyethylene matrices at low temperature",

abstract = "UV photolysis of CpMn(CO)3 (Cp = C5H5) in near critical liquid N2O at room temperature in both static and flow reactors leads to the formation of CpMn(CO)2(N2O) identified via ν(C-O) and ν(N2O) IR bands, the latter being recorded in low temperature polyethylene (PE) experiments. CpMn(CO)2(N2O) has a lifetime of ca. 5 min at room temperature in near-critical N2O and appears to have two decay pathways one of which leads to CpMn(CO)2(N2), possibly via O-transfer.",

author = "Karine Molvinger and Childs, {Gavin I.} and Margaret Jobling and Mark Roper and George, {Michael W.} and Martyn Poliakoff",

year = "2000",

doi = "10.1246/cl.2000.1260",

language = "English",

pages = "1260--1261",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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T1 - IR evidence for the generation of (C5H5)Mn(CO)2(N2O) in near-critical N2O at room temperature and in polyethylene matrices at low temperature

AU - Molvinger, Karine

AU - Childs, Gavin I.

AU - Jobling, Margaret

AU - Roper, Mark

AU - George, Michael W.

AU - Poliakoff, Martyn

PY - 2000

Y1 - 2000

N2 - UV photolysis of CpMn(CO)3 (Cp = C5H5) in near critical liquid N2O at room temperature in both static and flow reactors leads to the formation of CpMn(CO)2(N2O) identified via ν(C-O) and ν(N2O) IR bands, the latter being recorded in low temperature polyethylene (PE) experiments. CpMn(CO)2(N2O) has a lifetime of ca. 5 min at room temperature in near-critical N2O and appears to have two decay pathways one of which leads to CpMn(CO)2(N2), possibly via O-transfer.

AB - UV photolysis of CpMn(CO)3 (Cp = C5H5) in near critical liquid N2O at room temperature in both static and flow reactors leads to the formation of CpMn(CO)2(N2O) identified via ν(C-O) and ν(N2O) IR bands, the latter being recorded in low temperature polyethylene (PE) experiments. CpMn(CO)2(N2O) has a lifetime of ca. 5 min at room temperature in near-critical N2O and appears to have two decay pathways one of which leads to CpMn(CO)2(N2), possibly via O-transfer.

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U2 - 10.1246/cl.2000.1260

DO - 10.1246/cl.2000.1260

M3 - Article

AN - SCOPUS:0034344666

SN - 0366-7022

SP - 1260

EP - 1261

JO - Chemistry Letters

JF - Chemistry Letters

IS - 11

ER -

IR evidence for the generation of (C₅H₅)Mn(CO)₂(N₂O) in near-critical N₂O at room temperature and in polyethylene matrices at low temperature

Abstract

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