Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller

Mirza Nadeem Ahmad; Sohail Nadeem; Mohsin Javed; Shahid Iqbal; Sadaf ul Hassan; Samar O. Aljazzar; Eslam B. Elkaeed; Rami Adel Pashameah; Eman Alzahrani; Abd Elaziem Farouk; Mohammed T. Alotaibi; Hisham S.M. Abd-Rabboh

doi:10.3390/molecules27175477

Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller

Mirza Nadeem Ahmad, Sohail Nadeem, Mohsin Javed, Shahid Iqbal, Sadaf ul Hassan, Samar O. Aljazzar, Eslam B. Elkaeed, Rami Adel Pashameah, Eman Alzahrani, Abd Elaziem Farouk, Mohammed T. Alotaibi, Hisham S.M. Abd-Rabboh

Research output: Journal Publication › Article › peer-review

7 Citations (Scopus)

Abstract

The synthesis of MMT and poly(o-anisidine) (MMT/POA) clay nanocomposites was carried out by using the chemical oxidative polymerization of POA and MMT clay with POA, respectively. By maintaining the constant concentration of POA, different percentage loads of MMT clay were used to determine the effect of MMT clay on the properties of POA. The interaction between POA and MMT clay was investigated by FTIR spectroscopy, and, to reveal the complete compactness and homogeneous distribution of MMT clay in POA, were assessed by using scanning-electron-microscope (SEM) analysis. The UV–visible spectrum was studied for the optical and absorbance properties of MMT/POA ceramic nanocomposites. Furthermore, the horizontal burning test (HBT) demonstrated that clay nanofillers inhibit POA combustion.

Original language	English
Article number	5477
Journal	Molecules
Volume	27
Issue number	17
DOIs	https://doi.org/10.3390/molecules27175477
Publication status	Published - Sept 2022
Externally published	Yes

Keywords

(poly)ortho-anisidine
HBT
MMT (montmorillonite) clay
nanocomposites
nanofiller

ASJC Scopus subject areas

Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry

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10.3390/molecules27175477

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Ahmad, M. N., Nadeem, S., Javed, M., Iqbal, S., Hassan, S. U., Aljazzar, S. O., Elkaeed, E. B., Pashameah, R. A., Alzahrani, E., Farouk, A. E., Alotaibi, M. T., & Abd-Rabboh, H. S. M. (2022). Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller. Molecules, 27(17), Article 5477. https://doi.org/10.3390/molecules27175477

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title = "Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller",

abstract = "The synthesis of MMT and poly(o-anisidine) (MMT/POA) clay nanocomposites was carried out by using the chemical oxidative polymerization of POA and MMT clay with POA, respectively. By maintaining the constant concentration of POA, different percentage loads of MMT clay were used to determine the effect of MMT clay on the properties of POA. The interaction between POA and MMT clay was investigated by FTIR spectroscopy, and, to reveal the complete compactness and homogeneous distribution of MMT clay in POA, were assessed by using scanning-electron-microscope (SEM) analysis. The UV–visible spectrum was studied for the optical and absorbance properties of MMT/POA ceramic nanocomposites. Furthermore, the horizontal burning test (HBT) demonstrated that clay nanofillers inhibit POA combustion.",

keywords = "(poly)ortho-anisidine, HBT, MMT (montmorillonite) clay, nanocomposites, nanofiller",

author = "Ahmad, {Mirza Nadeem} and Sohail Nadeem and Mohsin Javed and Shahid Iqbal and Hassan, {Sadaf ul} and Aljazzar, {Samar O.} and Elkaeed, {Eslam B.} and Pashameah, {Rami Adel} and Eman Alzahrani and Farouk, {Abd Elaziem} and Alotaibi, {Mohammed T.} and Abd-Rabboh, {Hisham S.M.}",

note = "Publisher Copyright: {\textcopyright} 2022 by the authors.",

year = "2022",

month = sep,

doi = "10.3390/molecules27175477",

language = "English",

volume = "27",

journal = "Molecules",

issn = "1420-3049",

publisher = "MDPI Multidisciplinary Digital Publishing Institute",

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Ahmad, MN, Nadeem, S, Javed, M, Iqbal, S, Hassan, SU, Aljazzar, SO, Elkaeed, EB, Pashameah, RA, Alzahrani, E, Farouk, AE, Alotaibi, MT & Abd-Rabboh, HSM 2022, 'Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller', Molecules, vol. 27, no. 17, 5477. https://doi.org/10.3390/molecules27175477

TY - JOUR

T1 - Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller

AU - Ahmad, Mirza Nadeem

AU - Nadeem, Sohail

AU - Javed, Mohsin

AU - Iqbal, Shahid

AU - Hassan, Sadaf ul

AU - Aljazzar, Samar O.

AU - Elkaeed, Eslam B.

AU - Pashameah, Rami Adel

AU - Alzahrani, Eman

AU - Farouk, Abd Elaziem

AU - Alotaibi, Mohammed T.

AU - Abd-Rabboh, Hisham S.M.

PY - 2022/9

Y1 - 2022/9

N2 - The synthesis of MMT and poly(o-anisidine) (MMT/POA) clay nanocomposites was carried out by using the chemical oxidative polymerization of POA and MMT clay with POA, respectively. By maintaining the constant concentration of POA, different percentage loads of MMT clay were used to determine the effect of MMT clay on the properties of POA. The interaction between POA and MMT clay was investigated by FTIR spectroscopy, and, to reveal the complete compactness and homogeneous distribution of MMT clay in POA, were assessed by using scanning-electron-microscope (SEM) analysis. The UV–visible spectrum was studied for the optical and absorbance properties of MMT/POA ceramic nanocomposites. Furthermore, the horizontal burning test (HBT) demonstrated that clay nanofillers inhibit POA combustion.

AB - The synthesis of MMT and poly(o-anisidine) (MMT/POA) clay nanocomposites was carried out by using the chemical oxidative polymerization of POA and MMT clay with POA, respectively. By maintaining the constant concentration of POA, different percentage loads of MMT clay were used to determine the effect of MMT clay on the properties of POA. The interaction between POA and MMT clay was investigated by FTIR spectroscopy, and, to reveal the complete compactness and homogeneous distribution of MMT clay in POA, were assessed by using scanning-electron-microscope (SEM) analysis. The UV–visible spectrum was studied for the optical and absorbance properties of MMT/POA ceramic nanocomposites. Furthermore, the horizontal burning test (HBT) demonstrated that clay nanofillers inhibit POA combustion.

KW - (poly)ortho-anisidine

KW - HBT

KW - MMT (montmorillonite) clay

KW - nanocomposites

KW - nanofiller

UR - http://www.scopus.com/inward/record.url?scp=85137748645&partnerID=8YFLogxK

U2 - 10.3390/molecules27175477

DO - 10.3390/molecules27175477

M3 - Article

AN - SCOPUS:85137748645

SN - 1420-3049

VL - 27

JO - Molecules

JF - Molecules

IS - 17

M1 - 5477

ER -

Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller

Abstract

Keywords

ASJC Scopus subject areas

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