Fe-Based Metal-Organic Framework and Its Derivatives for Reversible Lithium Storage

Yan Jin, Chongchong Zhao, Yichao Lin, Deyu Wang, Liang Chen, Cai Shen

Research output: Journal PublicationArticlepeer-review

25 Citations (Scopus)

Abstract

The use of a Fe-based metal organic framework (MOF), namely MIL-88B(Fe), as active material for lithium ion batteries (LIBs) is reported for the first time in the present work. Fe-based MOF demonstrated high capacity, excellent cycling stability and rate performance when used as anode. A highly reversible capacity of ~680 mA h g1 after 500 cycles at a current density of 200 mA g1 was obtained. In addition, Fe2O3 and Fe3O4/C composites were obtained from Fe-based MOFs through thermal treatment. Both Fe2O3 and Fe3O4/C composites demonstrated high capacity and excellent cycling stability.

Original languageEnglish
Pages (from-to)768-774
Number of pages7
JournalJournal of Materials Science and Technology
Volume33
Issue number8
DOIs
Publication statusPublished - Aug 2017
Externally publishedYes

Keywords

  • Anode
  • Lithium ion battery
  • Metal organic framework
  • Metal oxide

ASJC Scopus subject areas

  • Ceramics and Composites
  • Mechanics of Materials
  • Mechanical Engineering
  • Polymers and Plastics
  • Metals and Alloys
  • Materials Chemistry

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