Abstract
Fast time-resolved IR (TRIR) spectroscopy is used to record ν(C-O) bands of the lowest lying excited state of [ClRe(CO)3(4,4′- bipyridyl)2] (half-life of approximately 1 μs in CH 2Cl2 solution); there is a shift of the ν(C-O) bands to higher frequency relative to the ground state, which is consistent with oxidation of the metal centre via electron transfer to the bipyridyl ligands.
Original language | English |
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Pages (from-to) | 1655-1657 |
Number of pages | 3 |
Journal | Chemical Communications |
Issue number | 21 |
DOIs | |
Publication status | Published - 1989 |
Externally published | Yes |
ASJC Scopus subject areas
- Molecular Medicine