Excited-state properties and reactivity of [ReCl(CO)3(2,2′-bipy)] (2,2′-bipy = 2,2′-bipyridyl) studied by time-resolved infrared spectroscopy

Michael W. George; Frank P.A. Johnson; Jeremy R. Westwell; P. Michael Hodges; James J. Turner

doi:10.1039/DT9930002977

Excited-state properties and reactivity of [ReCl(CO)₃(2,2′-bipy)] (2,2′-bipy = 2,2′-bipyridyl) studied by time-resolved infrared spectroscopy

Michael W. George, Frank P.A. Johnson, Jeremy R. Westwell, P. Michael Hodges, James J. Turner

Research output: Journal Publication › Article › peer-review

119 Citations (Scopus)

Abstract

Fast time-resolved infrared spectroscopy shows that the v(CO) bands of the important CO₂-reducing complex, [ReCl(CO)₃(2,2′-bipy)] 1 (2,2′-bipyridyl), shift up in frequency in the metal to ligand charge-transfer excited state and that the anion 1^-, generated by reaction of the excited state with triethylamine, shows a lowering in frequency of the v(CO) bands significantly different from those of related but non-reducing complexes.

Original language	English
Pages (from-to)	2977-2979
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	19
DOIs	https://doi.org/10.1039/DT9930002977
Publication status	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Excited-state properties and reactivity of [ReCl(CO)3(2,2′-bipy)] (2,2′-bipy = 2,2′-bipyridyl) studied by time-resolved infrared spectroscopy",

abstract = "Fast time-resolved infrared spectroscopy shows that the v(CO) bands of the important CO2-reducing complex, [ReCl(CO)3(2,2′-bipy)] 1 (2,2′-bipyridyl), shift up in frequency in the metal to ligand charge-transfer excited state and that the anion 1-, generated by reaction of the excited state with triethylamine, shows a lowering in frequency of the v(CO) bands significantly different from those of related but non-reducing complexes.",

author = "George, {Michael W.} and Johnson, {Frank P.A.} and Westwell, {Jeremy R.} and Hodges, {P. Michael} and Turner, {James J.}",

year = "1993",

doi = "10.1039/DT9930002977",

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journal = "Journal of the Chemical Society. Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Excited-state properties and reactivity of [ReCl(CO)3(2,2′-bipy)] (2,2′-bipy = 2,2′-bipyridyl) studied by time-resolved infrared spectroscopy

AU - George, Michael W.

AU - Johnson, Frank P.A.

AU - Westwell, Jeremy R.

AU - Hodges, P. Michael

AU - Turner, James J.

PY - 1993

Y1 - 1993

N2 - Fast time-resolved infrared spectroscopy shows that the v(CO) bands of the important CO2-reducing complex, [ReCl(CO)3(2,2′-bipy)] 1 (2,2′-bipyridyl), shift up in frequency in the metal to ligand charge-transfer excited state and that the anion 1-, generated by reaction of the excited state with triethylamine, shows a lowering in frequency of the v(CO) bands significantly different from those of related but non-reducing complexes.

AB - Fast time-resolved infrared spectroscopy shows that the v(CO) bands of the important CO2-reducing complex, [ReCl(CO)3(2,2′-bipy)] 1 (2,2′-bipyridyl), shift up in frequency in the metal to ligand charge-transfer excited state and that the anion 1-, generated by reaction of the excited state with triethylamine, shows a lowering in frequency of the v(CO) bands significantly different from those of related but non-reducing complexes.

UR - http://www.scopus.com/inward/record.url?scp=37049084570&partnerID=8YFLogxK

U2 - 10.1039/DT9930002977

DO - 10.1039/DT9930002977

M3 - Article

AN - SCOPUS:37049084570

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SP - 2977

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 19

ER -

Excited-state properties and reactivity of [ReCl(CO)₃(2,2′-bipy)] (2,2′-bipy = 2,2′-bipyridyl) studied by time-resolved infrared spectroscopy

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