Crystal structure, oxygen nonstoichiometry, and conductivity of mixed ionic-electronic conducting perovskite composites with CeO2

E. Konysheva, S. M. Francis, J. T.S. Irvine

Research output: Journal PublicationArticlepeer-review

17 Citations (Scopus)

Abstract

Conductivity, structure, and oxygen nonstoichiometry of compositions in the following series (100 - x) La0.6Sr0.4CoO 3±δ.xCeO2 (LSCCe) and (100 - x) La 0.6Sr0.4CoO3±δ.xCeO2 (LSMCe), where x = 0, 2, 5, and 10 mol %, are studied. CeO2 has a low solubility limit in the rhombohedral structure. Compositions containing more than 2 mol % ceria are two-phase and consist of a perovskite constituent with rhombohedral structure and ceria with cubic structure. Small additions of CeO2 influence the conductivity of the modified perovskites in a different way. The conductivity in the LSCCe series dramatically decreases with an addition of up to 10 mol % CeO2. However, the total conductivity in the LSMCe series only changes slightly. The conductivity of the perovskites as a function of oxygen partial pressure (0.21 to 1 × 10-4 atm) is discussed. Oxygen nonstoichiometry (δ) depending on temperature and oxygen partial pressure varies in the LSCCe series in a wider range (0<δ < 0.23) compared to that in the LSMCe series (0.06<δ <0.14). In contrast to the LSMCe series, the compositions in the LSCCe series show a strong relationship between lattice parameters, oxygen nonstoichiometry, and conductivity. X-ray photoelectron spectroscopy indicates that distortion of Co-O bonds takes place, which could affect electronic conductivity of perovskites.

Original languageEnglish
Pages (from-to)B159-B165
JournalJournal of the Electrochemical Society
Volume157
Issue number1
DOIs
Publication statusPublished - 2010
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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