Characteristics of starch-based films with different amylose contents plasticised by 1-ethyl-3-methylimidazolium acetate

Fengwei Xie, Bernadine M. Flanagan, Ming Li, Rowan W. Truss, Peter J. Halley, Michael J. Gidley, Tony McNally, Julia L. Shamshina, Robin D. Rogers

Research output: Journal PublicationArticlepeer-review

55 Citations (Scopus)

Abstract

Starch-based films plasticised by an ionic liquid, 1-ethyl-3-methylimidazolium acetate ([Emim][OAc]), were prepared by a simple compression moulding process, facilitated by the strong plasticisation effect of [Emim][OAc]. The effects of amylose content of starch (regular vs. high-amylose maize) and relative humidity (RH) during ageing of the samples on a range of structural and material characteristics were investigated. Surprisingly, plasticisation by [Emim][OAc] made the effect of amylose content insignificant, contrary to most previous studies when other plasticisers were used. In other words, [Emim][OAc] changed the underlying mechanism responsible for mechanical properties from the entanglement of starch macromolecules (mainly amylose), which has been reported as a main responsible factor previously. The crystallinity of the plasticised starch samples was low and thus was unlikely to have a major contribution to the material characteristics, although the amylose content impacted on the crystalline structure and the mobility of amorphous parts in the samples to some extent. Therefore, RH conditioning and thus the sample water content was the major factor influencing the mechanical properties, glass transition temperature, and electrical conductivity of the starch films. This suggests the potential application of ionic liquid-plasticised starch materials in areas where the control of properties by environmental RH is desired.

Original languageEnglish
Pages (from-to)160-168
Number of pages9
JournalCarbohydrate Polymers
Volume122
DOIs
Publication statusPublished - 20 May 2015
Externally publishedYes

Keywords

  • 1-Ethyl-3-methylimidazolium acetate
  • Amylose/amylopectin ratio
  • Ionic liquid
  • Plasticisation
  • Relative humidity
  • Starch

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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