A systematic approach to the generation of long-lived metal alkane complexes: Combined IR and NMR study of (Tp)Re(CO)2(cyclopentane)

Simon B. Duckett; Michael W. George; Omar S. Jina; Steven L. Matthews; Robin N. Perutz; Xue Zhong Sun; Khuong Q. Vuong

doi:10.1039/b819671k

A systematic approach to the generation of long-lived metal alkane complexes: Combined IR and NMR study of (Tp)Re(CO)₂(cyclopentane)

Simon B. Duckett, Michael W. George, Omar S. Jina, Steven L. Matthews, Robin N. Perutz, Xue Zhong Sun, Khuong Q. Vuong

Department of Chemical and Environmental Engineering

Research output: Journal Publication › Article › peer-review

22 Citations (Scopus)

Abstract

Short wavelength photolysis of (Tp)Re(CO)₃ (Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyclopentane yielded (Tp)Re(CO)₂(cyclopentane), an alkane complex with three nitrogen ligands that was characterised by NMR spectroscopy.

Original language	English
Pages (from-to)	1401-1403
Number of pages	3
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/b819671k
Publication status	Published - 2009

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry (all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "A systematic approach to the generation of long-lived metal alkane complexes: Combined IR and NMR study of (Tp)Re(CO)2(cyclopentane)",

abstract = "Short wavelength photolysis of (Tp)Re(CO)3 (Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyclopentane yielded (Tp)Re(CO)2(cyclopentane), an alkane complex with three nitrogen ligands that was characterised by NMR spectroscopy.",

author = "Duckett, {Simon B.} and George, {Michael W.} and Jina, {Omar S.} and Matthews, {Steven L.} and Perutz, {Robin N.} and Sun, {Xue Zhong} and Vuong, {Khuong Q.}",

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journal = "Chemical Communications",

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T2 - Combined IR and NMR study of (Tp)Re(CO)2(cyclopentane)

AU - Duckett, Simon B.

AU - George, Michael W.

AU - Jina, Omar S.

AU - Matthews, Steven L.

AU - Perutz, Robin N.

AU - Sun, Xue Zhong

AU - Vuong, Khuong Q.

PY - 2009

Y1 - 2009

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AB - Short wavelength photolysis of (Tp)Re(CO)3 (Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyclopentane yielded (Tp)Re(CO)2(cyclopentane), an alkane complex with three nitrogen ligands that was characterised by NMR spectroscopy.

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DO - 10.1039/b819671k

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AN - SCOPUS:61849099483

SN - 1359-7345

SP - 1401

EP - 1403

JO - Chemical Communications

JF - Chemical Communications

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ER -

A systematic approach to the generation of long-lived metal alkane complexes: Combined IR and NMR study of (Tp)Re(CO)₂(cyclopentane)

Abstract

ASJC Scopus subject areas

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