A systematic approach to the generation of long-lived metal alkane complexes: Combined IR and NMR study of (Tp)Re(CO)2(cyclopentane)

Simon B. Duckett, Michael W. George, Omar S. Jina, Steven L. Matthews, Robin N. Perutz, Xue Zhong Sun, Khuong Q. Vuong

Research output: Journal PublicationArticlepeer-review

19 Citations (Scopus)

Abstract

Short wavelength photolysis of (Tp)Re(CO)3 (Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyclopentane yielded (Tp)Re(CO)2(cyclopentane), an alkane complex with three nitrogen ligands that was characterised by NMR spectroscopy.

Original languageEnglish
Pages (from-to)1401-1403
Number of pages3
JournalChemical Communications
Issue number11
DOIs
Publication statusPublished - 2009
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry (all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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