A simple coupled ANNs-RSM approach in modeling product distribution of Fischer-Tropsch synthesis using a microchannel reactor with Ru-promoted Co/Al2O3 catalyst

Yong Sun, Gang Yang, Mengxia Xu, Jian Xu, Zhi Sun

Research output: Journal PublicationArticlepeer-review

14 Citations (Scopus)

Abstract

A simple approach using hybrid artificial neural networks (ANNs)-response surface methodology (RSM) was developed to model the detailed product distribution using Ru-promoted cobalt-based catalyst with Al2O3 as the support in a microchannel reactor for Fischer-Tropsch (FT) synthesis. Using the independent process parameters for training, the established model is capable of predicting hydrocarbon production distributions, ie, paraffin formation rate (C2-C15) and olefin to paraffin ratio (OPR C2-C15) within acceptable uncertainties. The ANNs-RSM model and comprehensive mechanistic model using the Langmuir-Hinshelwood-Hougen-Watson (LHHW) approach were compared to identify a few inherent advantages of the proposed model in modeling complex FT synthesis. The proposed ANNs-RSM model shows its appealing merits, ie, faster converge and higher accuracy (less than ±10% uncertainties was achieved from ANNs-RSM model, while LHHW model achieved less than ±15% uncertainties except a few exceptional high errors uncertainties at certain experimental conditions). The statistical significances to the product distributions and hydrocarbon formation rate during FT synthesis could be easily identified and quantitatively analyzed by the established ANNs-RSM model. The future effective alternative of kinetic study of the complex system such as FT synthesis in the microstructured reactor might follow the methods of using empirical reliable approach for process optimization together with mechanistic kinetic study for detailed reaction pathway discrimination.

Original languageEnglish
Pages (from-to)1046-1061
Number of pages16
JournalInternational Journal of Energy Research
Volume44
Issue number2
DOIs
Publication statusPublished - 1 Feb 2020

Keywords

  • ANNs-RSM
  • Fischer-Tropsch synthesis
  • cobalt catalyst
  • comprehensive kinetics
  • microchannel reactor

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Fuel Technology
  • Energy Engineering and Power Technology

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