(2,2′-Bipyridyl)dicarbonylbis(triethoxyphosphine-κP)-rhenium(I) hexafluorophosphate

Alexander J. Blake; Michael W. George; Marina K. Kuimova; Colleen A. Williams; Claire Wilson

doi:10.1107/S1600536805030643

(2,2′-Bipyridyl)dicarbonylbis(triethoxyphosphine-κP)-rhenium(I) hexafluorophosphate

Alexander J. Blake, Michael W. George, Marina K. Kuimova, Colleen A. Williams, Claire Wilson

Research output: Journal Publication › Article › peer-review

Abstract

In the title compound, [Re(C₁₀H₈N₂)(C ₆H₁₅O₃P)₂(CO)₂]PF ₆, the carbonyl ligands are mutually cis and lie trans to the N donors of the 2,2′-bipyridyl ligand, while the triethoxy-phosphine ligands are mutually trans. The Re^I centres exhibit approximate octahedral coordination, the major distortions from which arise from the narrow bite angle of the 2,2′-bipyridyl ligand which is expressed in the N-Re-N angles of 74.0 (3) and 74.3 (3)°. There are two cations and two anions in the asymmetric unit. The title compound is of interest because it has been shown to be a photocatalyst for CO₂ reduction [Ishitani, George, Ibusuki, Johnson, Koike, Nozaki, Pac, Turner & Westwell (1994). Inorg. Chem. 33, 4712-4717].

Original language	English
Pages (from-to)	m2196-m2197
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	11
DOIs	https://doi.org/10.1107/S1600536805030643
Publication status	Published - 1 Nov 2005
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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@article{db3d0c14fbf24c648fb2957da6965650,

title = "(2,2′-Bipyridyl)dicarbonylbis(triethoxyphosphine-κP)-rhenium(I) hexafluorophosphate",

abstract = "In the title compound, [Re(C10H8N2)(C 6H15O3P)2(CO)2]PF 6, the carbonyl ligands are mutually cis and lie trans to the N donors of the 2,2′-bipyridyl ligand, while the triethoxy-phosphine ligands are mutually trans. The ReI centres exhibit approximate octahedral coordination, the major distortions from which arise from the narrow bite angle of the 2,2′-bipyridyl ligand which is expressed in the N-Re-N angles of 74.0 (3) and 74.3 (3)°. There are two cations and two anions in the asymmetric unit. The title compound is of interest because it has been shown to be a photocatalyst for CO2 reduction [Ishitani, George, Ibusuki, Johnson, Koike, Nozaki, Pac, Turner & Westwell (1994). Inorg. Chem. 33, 4712-4717].",

author = "Blake, {Alexander J.} and George, {Michael W.} and Kuimova, {Marina K.} and Williams, {Colleen A.} and Claire Wilson",

year = "2005",

month = nov,

day = "1",

doi = "10.1107/S1600536805030643",

language = "English",

volume = "61",

pages = "m2196--m2197",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - (2,2′-Bipyridyl)dicarbonylbis(triethoxyphosphine-κP)-rhenium(I) hexafluorophosphate

AU - Blake, Alexander J.

AU - George, Michael W.

AU - Kuimova, Marina K.

AU - Williams, Colleen A.

AU - Wilson, Claire

PY - 2005/11/1

Y1 - 2005/11/1

N2 - In the title compound, [Re(C10H8N2)(C 6H15O3P)2(CO)2]PF 6, the carbonyl ligands are mutually cis and lie trans to the N donors of the 2,2′-bipyridyl ligand, while the triethoxy-phosphine ligands are mutually trans. The ReI centres exhibit approximate octahedral coordination, the major distortions from which arise from the narrow bite angle of the 2,2′-bipyridyl ligand which is expressed in the N-Re-N angles of 74.0 (3) and 74.3 (3)°. There are two cations and two anions in the asymmetric unit. The title compound is of interest because it has been shown to be a photocatalyst for CO2 reduction [Ishitani, George, Ibusuki, Johnson, Koike, Nozaki, Pac, Turner & Westwell (1994). Inorg. Chem. 33, 4712-4717].

AB - In the title compound, [Re(C10H8N2)(C 6H15O3P)2(CO)2]PF 6, the carbonyl ligands are mutually cis and lie trans to the N donors of the 2,2′-bipyridyl ligand, while the triethoxy-phosphine ligands are mutually trans. The ReI centres exhibit approximate octahedral coordination, the major distortions from which arise from the narrow bite angle of the 2,2′-bipyridyl ligand which is expressed in the N-Re-N angles of 74.0 (3) and 74.3 (3)°. There are two cations and two anions in the asymmetric unit. The title compound is of interest because it has been shown to be a photocatalyst for CO2 reduction [Ishitani, George, Ibusuki, Johnson, Koike, Nozaki, Pac, Turner & Westwell (1994). Inorg. Chem. 33, 4712-4717].

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DO - 10.1107/S1600536805030643

M3 - Article

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SN - 1600-5368

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SP - m2196-m2197

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

(2,2′-Bipyridyl)dicarbonylbis(triethoxyphosphine-κP)-rhenium(I) hexafluorophosphate

Abstract

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UN SDGs

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