TY - JOUR
T1 - 共价有机聚合物/石墨烯复合材料的制备及锂电性能研究
AU - Gao, Guoliang
AU - Zhang, Haitao
AU - Li, Chenbin
AU - Wang, Deyu
AU - Shen, Cai
N1 - Funding Information:
摇 This work was financially supported by the Natural Science Foundation of Ningbo (2018A610011) and the Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure (SKL201805SIC).
Publisher Copyright:
© 2020, Materials Review Magazine. All right reserved.
PY - 2020/3/25
Y1 - 2020/3/25
N2 - Covalent organic polymer (COPs) is a kind of crystalline microporous polymer, which has been widely used due to its many excellent properties, such as high specific surface area, abundant pore size structure, low weight density. Here, melamine-based COPs with the lamellar structure were synthesized using melamine and 1,4-dibromobutane. The thickness of the flake is about 3.5 nm. COPs/rGO composites were prepared by in situ doping graphene (rGO) and the electrochemical performance as a lithium-ion battery anode materials was studied. The composite materials show a reversible capacity of 420 mAh/g after 100 cycles at a current density of 50 mA/g, at the same time, it shows excellent high current density and rate capability.
AB - Covalent organic polymer (COPs) is a kind of crystalline microporous polymer, which has been widely used due to its many excellent properties, such as high specific surface area, abundant pore size structure, low weight density. Here, melamine-based COPs with the lamellar structure were synthesized using melamine and 1,4-dibromobutane. The thickness of the flake is about 3.5 nm. COPs/rGO composites were prepared by in situ doping graphene (rGO) and the electrochemical performance as a lithium-ion battery anode materials was studied. The composite materials show a reversible capacity of 420 mAh/g after 100 cycles at a current density of 50 mA/g, at the same time, it shows excellent high current density and rate capability.
KW - Covalent organic polymer
KW - Electrochemical performance
KW - Graphene
KW - Lithium-ion batteries
UR - http://www.scopus.com/inward/record.url?scp=85082602608&partnerID=8YFLogxK
U2 - 10.11896/cldb.19010153
DO - 10.11896/cldb.19010153
M3 - 文章
AN - SCOPUS:85082602608
SN - 1005-023X
VL - 34
SP - 6161
EP - 6165
JO - Cailiao Daobao/Materials Review
JF - Cailiao Daobao/Materials Review
IS - 3
ER -