Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems

Marina K. Kuimova; Wassim Z. Alsindi; Joanne Dyer; David C. Grills; Omar S. Jina; Pavel Matousek; Anthony W. Parker; Peter Portius; Xue Zhong Sun; Michael Towrie; Claire Wilson; Jixin Yang; Michael W. George

doi:10.1039/b306303h

Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems

Marina K. Kuimova
, Wassim Z. Alsindi
, Joanne Dyer
, David C. Grills
, Omar S. Jina
, Pavel Matousek
, Anthony W. Parker
, Peter Portius
, Xue Zhong Sun
, Michael Towrie
, Claire Wilson
, Jixin Yang
, Michael W. George

Research output: Journal Publication › Article › peer-review

83 Citations (Scopus)

Abstract

Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast infrared detection, is a powerful technique for probing excited states and detecting reaction intermediates. In this Perspective we highlight the application of TRIR to excited states by probing the nature of the lowest excited states of fac-[Re(CO)₃(dppz-Cl₂)(R)]ⁿ⁺ (R = Cl− (n = 0), py (n = 1) and 4-Me₂N-py (n = 1) dppz-Cl₂ = 11,12-dichlorodipyrido[3,2-a:2′,3′-c]phenazine) in CH₃CN. The characterisation of [Cr(η⁶-C₆H₆)(CO)₂Xe] and [Re(η⁵-C₅H₅)(CO)₂(C₂H₆)] in supercritical Xe and liquid ethane solution exemplifies how this technique can be applied to detect new organometallic species.

Original language	English
Pages (from-to)	3996-4006
Number of pages	11
Journal	Dalton Transactions
Volume	3
Issue number	21
DOIs	https://doi.org/10.1039/b306303h
Publication status	Published - 22 Oct 2003
Externally published	Yes

Free Keywords

Chromiun
Kinetics
Photochemistry, photophysics
Rhenium
Vibrational spectroscopy

ASJC Scopus subject areas

General Chemistry

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10.1039/b306303h

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Kuimova, M. K., Alsindi, W. Z., Dyer, J., Grills, D. C., Jina, O. S., Matousek, P., Parker, A. W., Portius, P., Zhong Sun, X., Towrie, M., Wilson, C., Yang, J., & George, M. W. (2003). Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems. Dalton Transactions, 3(21), 3996-4006. https://doi.org/10.1039/b306303h

@article{031102e77788490ea4bba08df8a1a3d0,

title = "Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems",

abstract = "Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast infrared detection, is a powerful technique for probing excited states and detecting reaction intermediates. In this Perspective we highlight the application of TRIR to excited states by probing the nature of the lowest excited states of fac-[Re(CO)3(dppz-Cl2)(R)]n+ (R = Cl− (n = 0), py (n = 1) and 4-Me2N-py (n = 1) dppz-Cl2 = 11,12-dichlorodipyrido[3,2-a:2′,3′-c]phenazine) in CH3CN. The characterisation of [Cr(η6-C6H6)(CO)2Xe] and [Re(η5-C5H5)(CO)2(C2H6)] in supercritical Xe and liquid ethane solution exemplifies how this technique can be applied to detect new organometallic species.",

keywords = "Chromiun, Kinetics, Photochemistry, photophysics, Rhenium, Vibrational spectroscopy",

author = "Kuimova, \{Marina K.\} and Alsindi, \{Wassim Z.\} and Joanne Dyer and Grills, \{David C.\} and Jina, \{Omar S.\} and Pavel Matousek and Parker, \{Anthony W.\} and Peter Portius and \{Zhong Sun\}, Xue and Michael Towrie and Claire Wilson and Jixin Yang and George, \{Michael W.\}",

year = "2003",

month = oct,

day = "22",

doi = "10.1039/b306303h",

language = "English",

volume = "3",

pages = "3996--4006",

journal = "Dalton Transactions",

issn = "1477-9226",

number = "21",

}

Kuimova, MK, Alsindi, WZ, Dyer, J, Grills, DC, Jina, OS, Matousek, P, Parker, AW, Portius, P, Zhong Sun, X, Towrie, M, Wilson, C, Yang, J & George, MW 2003, 'Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems', Dalton Transactions, vol. 3, no. 21, pp. 3996-4006. https://doi.org/10.1039/b306303h

TY - JOUR

T1 - Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems

AU - Kuimova, Marina K.

AU - Alsindi, Wassim Z.

AU - Dyer, Joanne

AU - Grills, David C.

AU - Jina, Omar S.

AU - Matousek, Pavel

AU - Parker, Anthony W.

AU - Portius, Peter

AU - Zhong Sun, Xue

AU - Towrie, Michael

AU - Wilson, Claire

AU - Yang, Jixin

AU - George, Michael W.

PY - 2003/10/22

Y1 - 2003/10/22

N2 - Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast infrared detection, is a powerful technique for probing excited states and detecting reaction intermediates. In this Perspective we highlight the application of TRIR to excited states by probing the nature of the lowest excited states of fac-[Re(CO)3(dppz-Cl2)(R)]n+ (R = Cl− (n = 0), py (n = 1) and 4-Me2N-py (n = 1) dppz-Cl2 = 11,12-dichlorodipyrido[3,2-a:2′,3′-c]phenazine) in CH3CN. The characterisation of [Cr(η6-C6H6)(CO)2Xe] and [Re(η5-C5H5)(CO)2(C2H6)] in supercritical Xe and liquid ethane solution exemplifies how this technique can be applied to detect new organometallic species.

AB - Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast infrared detection, is a powerful technique for probing excited states and detecting reaction intermediates. In this Perspective we highlight the application of TRIR to excited states by probing the nature of the lowest excited states of fac-[Re(CO)3(dppz-Cl2)(R)]n+ (R = Cl− (n = 0), py (n = 1) and 4-Me2N-py (n = 1) dppz-Cl2 = 11,12-dichlorodipyrido[3,2-a:2′,3′-c]phenazine) in CH3CN. The characterisation of [Cr(η6-C6H6)(CO)2Xe] and [Re(η5-C5H5)(CO)2(C2H6)] in supercritical Xe and liquid ethane solution exemplifies how this technique can be applied to detect new organometallic species.

KW - Chromiun

KW - Kinetics

KW - Photochemistry, photophysics

KW - Rhenium

KW - Vibrational spectroscopy

UR - https://www.scopus.com/pages/publications/0242695595

U2 - 10.1039/b306303h

DO - 10.1039/b306303h

M3 - Article

AN - SCOPUS:0242695595

SN - 1477-9226

VL - 3

SP - 3996

EP - 4006

JO - Dalton Transactions

JF - Dalton Transactions

IS - 21

ER -

Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems

Abstract

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