Ultrafast IR spectroscopy of the short-lived transients formed by UV excitation of cytosine derivatives

Susan Quinn; Gerard W. Doorley; Graeme W. Watson; Alexander J. Cowan; Michael W. George; Anthony W. Parker; Kate L. Ronayne; Michael Towrie; John M. Kelly

doi:10.1039/b703344c

Ultrafast IR spectroscopy of the short-lived transients formed by UV excitation of cytosine derivatives

Susan Quinn, Gerard W. Doorley, Graeme W. Watson, Alexander J. Cowan, Michael W. George, Anthony W. Parker, Kate L. Ronayne, Michael Towrie, John M. Kelly

Research output: Journal Publication › Article › peer-review

48 Citations (Scopus)

Abstract

A strong infrared band at 1574 cm^-1 is observed following 267 nm excitation of 2′-deoxycytidine (τ = 37 ± 4 ps) or 2′-deoxycytidine 5′-monophosphate (τ = 33 ± 4 ps); this band is provisionally attributed to an ¹n_Nπ* state and is absent for cytosine.

Original language	English
Pages (from-to)	2130-2132
Number of pages	3
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/b703344c
Publication status	Published - 2007
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b703344c

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title = "Ultrafast IR spectroscopy of the short-lived transients formed by UV excitation of cytosine derivatives",

abstract = "A strong infrared band at 1574 cm-1 is observed following 267 nm excitation of 2′-deoxycytidine (τ = 37 ± 4 ps) or 2′-deoxycytidine 5′-monophosphate (τ = 33 ± 4 ps); this band is provisionally attributed to an 1nNπ* state and is absent for cytosine.",

author = "Susan Quinn and Doorley, \{Gerard W.\} and Watson, \{Graeme W.\} and Cowan, \{Alexander J.\} and George, \{Michael W.\} and Parker, \{Anthony W.\} and Ronayne, \{Kate L.\} and Michael Towrie and Kelly, \{John M.\}",

year = "2007",

doi = "10.1039/b703344c",

language = "English",

pages = "2130--2132",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "21",

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T1 - Ultrafast IR spectroscopy of the short-lived transients formed by UV excitation of cytosine derivatives

AU - Quinn, Susan

AU - Doorley, Gerard W.

AU - Watson, Graeme W.

AU - Cowan, Alexander J.

AU - George, Michael W.

AU - Parker, Anthony W.

AU - Ronayne, Kate L.

AU - Towrie, Michael

AU - Kelly, John M.

PY - 2007

Y1 - 2007

N2 - A strong infrared band at 1574 cm-1 is observed following 267 nm excitation of 2′-deoxycytidine (τ = 37 ± 4 ps) or 2′-deoxycytidine 5′-monophosphate (τ = 33 ± 4 ps); this band is provisionally attributed to an 1nNπ* state and is absent for cytosine.

AB - A strong infrared band at 1574 cm-1 is observed following 267 nm excitation of 2′-deoxycytidine (τ = 37 ± 4 ps) or 2′-deoxycytidine 5′-monophosphate (τ = 33 ± 4 ps); this band is provisionally attributed to an 1nNπ* state and is absent for cytosine.

UR - https://www.scopus.com/pages/publications/34548222533

U2 - 10.1039/b703344c

DO - 10.1039/b703344c

M3 - Article

C2 - 17520112

AN - SCOPUS:34548222533

SN - 1359-7345

SP - 2130

EP - 2132

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Ultrafast IR spectroscopy of the short-lived transients formed by UV excitation of cytosine derivatives

Abstract

ASJC Scopus subject areas

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